Synthesis, Characterization, Thermal Analysis and Structural Studies of New Complexes with Tetradentate Ligand

A. Salih Al-Hamdani, Abbas; S. Hassan, Sahar

	Synthesis, Characterization, Thermal Analysis and Structural Studies of New Complexes with Tetradentate Ligand
Baghdad Science Journal
Article 1, Volume 12, Issue 2, 2015, Pages 379-393
Authors
Abbas A. Salih Al-Hamdani; Sahar S. Hassan
Abstract
Some new complexes of 4-(5-(1,5-dimethyl-3-oxo-2-phenyl pyrazolidin-4- ylimino)-3,3-dimethyl cyclohexylideneamino) -1,5- dimethyl-2- phenyl -1H- pyrazol -3(2H) –one (L) with Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Pd(II), Re(V) and Pt(IV) were prepared. The ligand and its metal complexes were characterized by phisco- chemical spectroscopic techniques. The spectral data were suggested that the (L) as a neutral tetradentate ligand is coordinated with the metal ions through two nitrogen and two oxygen atoms. These studies revealed Octahedral geometries for all metal complexes, except square planar for Pd(II) complex. Moreover, the thermodynamic activation parameters, such as ΔE*, ΔH, ΔS, ΔG and K are calculated from the TGA curves using Coats –Redfern method. Hyper Chem -8 program has been used to predict structural geometries for compounds in gas phase. The heat of formation (ΔHf) and bin ding energy (ΔEb) at 298 °K for the free ligand and its metal complexes were calculated by PM3 method. The synthesized ligands and their metal complexes were screened for their biological activity against bacterial species, two Gram positive bacteria (Bacillus subtilis and Staphylococcus aureus) and two Gram negative bacteria (Escherichia coli and Pseudomonas aeruginosa).
Keywords
Tetradentate ligand Schiff base; thermal analysis and Kinetics thermodynamic parameters

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