Recycling of an Effluent Soot from Kademia Diesel-Power Plant as a Carbon Source for the Synthesis and Characterization of NanoCarbon

Sharif Hamadi, Adel

doi:10.30684/etj.32.3B.1

	Recycling of an Effluent Soot from Kademia Diesel-Power Plant as a Carbon Source for the Synthesis and Characterization of NanoCarbon
Engineering and Technology Journal
Article 1, Volume 32, 3B, 2014, Pages 386-395 PDF (428.25 K)
DOI: 10.30684/etj.32.3B.1
Author
Adel Sharif Hamadi
Abstract
Soot obtained as an effluent from Kademia diesel-power station was recycled and utilized as feedstock for preparation of nano carbon particles. The porosity, surface area analysis featured by BET N2 adsorption, proximate analysis, Fourier Tranform Infrared Spectroscopy (FTIR), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM) were employed for the structural and morphological characterization of the halocarbon formed. Ultimate analysis of the fuel oil samples indicate that the H/C ratio of nanospheres is less 0.085 which is an indication of crystallization in the nanomaterial formed. The results obtained from BET analysis had specific surface area increases to 50 m2/g, comparing with 28 m2/g of that the raw soot. SEM results shows a variations in size and shape of nanocarbon particles formed. The FTIR spectrum of soot shows characteristic signals in the range of 400-4000 cm-1 where corresponding to SO4 2- (600 cm-1), NO3 - (850 cm-1), CO3 2- (900 cm-1), SiO4 4- (1050 cm-1), C–OH aromatics (1250 cm-1), NO3 - (1300 cm-1), CO3 2- (1650 and 1720 cm-1), C=CH alkenes (2930 cm-1), and C – OH alcohols (3400 and 3550 cm-1). XRD investigation indicates the presence of large amount of amorphous material in association with nanocarbon at moderately high intensity broad peak; 2θ=23.5140o, where at the low intensity; 2θ=48.6389o indicate of the low quality of nanomaterial presented in the soot.
Keywords
Diesel Soot; NanoCarbon; Characterization; XRD; SEM; FTIR

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