M. Sarhan, B., M. Lateef, S., J. Waheed, E. (2015). Synthesis and Characterization of Some Metal Complexes of [N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-ylcarbamothioyl) acetamide]. , 28(2), 102-115.
Basima M. Sarhan; Sajid M. Lateef; Enass J. Waheed. "Synthesis and Characterization of Some Metal Complexes of [N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-ylcarbamothioyl) acetamide]". , 28, 2, 2015, 102-115.
M. Sarhan, B., M. Lateef, S., J. Waheed, E. (2015). 'Synthesis and Characterization of Some Metal Complexes of [N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-ylcarbamothioyl) acetamide]', , 28(2), pp. 102-115.
M. Sarhan, B., M. Lateef, S., J. Waheed, E. Synthesis and Characterization of Some Metal Complexes of [N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-ylcarbamothioyl) acetamide]. , 2015; 28(2): 102-115.

Synthesis and Characterization of Some Metal Complexes of [N-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-ylcarbamothioyl) acetamide]

Ibn Al-Haitham Journal For Pure And Applied Science
Article 1, Volume 28, Issue 2, 2015, Pages 102-115
Authors
Basima M. Sarhan; Sajid M. Lateef; Enass J. Waheed
Abstract
A new ligand [N- (1,5- dimethyl -3- oxo- 2 – phenyl - 2 ,3 – dihydro -1H- pyrazol -4-ylcarbamothioyl) acetamide] (AAD) was synthesized by reaction of acetyl isothiocyanate with 4-aminoantipyrine, The ligand was characterized by micro elemental analysis C.H.N.S., FT-IR ,UV-Vis and 1H-13CNMR spectra, some transition metals complex of this ligand were prepared and characterized by FT-IR, UV-Vis spectra, conductivity measurements, magnetic susceptibility and atomic absorption. From the obtained results the molecular formula of all prepared complexes were [M(AAD)2(H2O)2]Cl2 (M+2 = Mn, Co, Ni, Cu, Zn, Cd and Hg),the proposed geometrical structure for all complexes were octahedral.
Keywords
Aminoantipyrine; acetyl isothiocyanate; complexes
Statistics
Article View: 55
PDF Download: 25


Journal Management System. Powered by iJournalPro.com