Musa, A., Mohy, T. (2009). SYNTHESIS AND CHARACERISATION OF NOVEL PENTADENTATELIGAND TYPE N2S2O 4-METHYL-2,6- BIS[4-METHYLTHIOSEMICARBAZONYLIDEN]- PHENOL AND THEIR COMPLEXESWITH Ni+2, Pd+2, Cu+2, Zn+2, Cd+2 and Hg+2. , 12(2), 25-34.
Aldin. Musa; Taghreed Mohy. "SYNTHESIS AND CHARACERISATION OF NOVEL PENTADENTATELIGAND TYPE N2S2O 4-METHYL-2,6- BIS[4-METHYLTHIOSEMICARBAZONYLIDEN]- PHENOL AND THEIR COMPLEXESWITH Ni+2, Pd+2, Cu+2, Zn+2, Cd+2 and Hg+2". , 12, 2, 2009, 25-34.
Musa, A., Mohy, T. (2009). 'SYNTHESIS AND CHARACERISATION OF NOVEL PENTADENTATELIGAND TYPE N2S2O 4-METHYL-2,6- BIS[4-METHYLTHIOSEMICARBAZONYLIDEN]- PHENOL AND THEIR COMPLEXESWITH Ni+2, Pd+2, Cu+2, Zn+2, Cd+2 and Hg+2', , 12(2), pp. 25-34.
Musa, A., Mohy, T. SYNTHESIS AND CHARACERISATION OF NOVEL PENTADENTATELIGAND TYPE N2S2O 4-METHYL-2,6- BIS[4-METHYLTHIOSEMICARBAZONYLIDEN]- PHENOL AND THEIR COMPLEXESWITH Ni+2, Pd+2, Cu+2, Zn+2, Cd+2 and Hg+2. , 2009; 12(2): 25-34.

SYNTHESIS AND CHARACERISATION OF NOVEL PENTADENTATELIGAND TYPE N2S2O 4-METHYL-2,6- BIS[4-METHYLTHIOSEMICARBAZONYLIDEN]- PHENOL AND THEIR COMPLEXESWITH Ni+2, Pd+2, Cu+2, Zn+2, Cd+2 and Hg+2

Journal of Al-Nahrain University - Science
Article 1, Volume 12, Issue 2, 2009, Pages 25-34
Authors
Aldin. Musa; Taghreed Mohy
Abstract
AbstractTwo equivalent of 4-methyl thiosemicarbazide was reacted with 2,6-diformyl-4-methyl phenolto give the new pentadentate ligand H3L type N2S2O {where H3L= 4-methyl-2,6- Bis[4-methylthiosemicarbazonyliden]-phenol. Also complexes of the ligand of H3L in general formula[M HnLX]y where M=Ni+2, Cu+2, n=2, X=Cl, y=0; M=, pd+2 , Zn+2, Cd+2 and Hg+2 ions , n=3, X=0,y=+2 were prepared. All complexes and ligand have been characterised by spectroscopy methods{IR, UV-Vis, 1H, 13C, 1H-13C NMR spectroscopy}, atomic absorption, microanalysis of elements(C.H.N), along with conductivity measurement. From the above data, the proposed molecularstructure for Ni+2 and Cu2 ions are octahedral, pd+2 complexes is square planner, while Zn+2 ,Cd+2,Hg+2 complexes are forming distorted tetrahedral.
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