- All Journals
- Al-Qadisiyah University
- Basrah University
- Kirkuk University
- Mosul University
- The Iraqi Borad for Medical Specialization
- University of Anbar
- University of Technology
- Al Mustafa University
- Al-Zahraa University for Women
- Alnoor University
- Kunooz University
- Misan University
- Ninevah University
- Tikrit University
- University of Al-Hamdaniya
- University of Kerbala
Preparation and Characterization of 7-[2-Amino – 1,3,4 Thiadiazole – 5 – yl – Dithio Acetamido] Desacetoxy Cephalosporanic Acid Complexes with Fe(III), Ti(III) and Cr(III) ions | ||
| Diyala Journal For Pure Science | ||
| Article 1, Volume 11, Issue 1, 2015, Pages 58-68 | ||
| Authors | ||
| Iebtehal K. A; Afraa S. Sh; Jawdat H. A | ||
| Abstract | ||
| The synthesis and characterization of new complexes of Fe3+, Ti3+ and Cr3+ with the ligand of 7-[2-amino - 1,3,4 - thiadiazole - 5 - yl - dithio acetamido] desacetoxy cephalosporanic acid (cephalo H) in both neutral and basic medium were described. The complexes are of the general formula [M (cepahlo H) Cl2] Cl and [M (cephalo H) Cl2] [where M = Fe3+, Ti3+ and Cr3+; cephalo H = 7-[2-amino - 1,3,4 - thiadiazole - 5 - yl - dithio acetamido] desacetoxy cephalosporanic acid; cephalo = deprotonated of cephalo H. They are characterized by elemental analysis, molar conductivity and infrared spectrum. The ligand exhibited a tetradentate manner forming the most probable hexacoordinated geometry. | ||
| Keywords | ||
| Cephalo; cephalosporanic acid and; thiadiazole | ||
|
Statistics Article View: 179 PDF Download: 136 |
||