- All Journals
- Al-Qadisiyah University
- Basrah University
- Kirkuk University
- Mosul University
- The Iraqi Borad for Medical Specialization
- University of Anbar
- University of Technology
- Al Mustafa University
- Al-Zahraa University for Women
- Alnoor University
- Kunooz University
- Misan University
- Ninevah University
- Tikrit University
- University of Al-Hamdaniya
- University of Kerbala
Synthesis and Characterization of Palladium (II) Complexes Containing Mixed Ligands of diphosphine-monoxides and Saccharine or thiosaccharine | ||
| Diyala Journal For Pure Science | ||
| Article 1, Volume 11, Issue 3, 2015, Pages 77-95 | ||
| Author | ||
| Mousa S. Hussein | ||
| Abstract | ||
| Two complexes of the type [PdCl2(L)2] L=dppmO,dppeO were prepared from the reaction of with the ligands(dppmO;bis(diphenylphosphino) [PdCl2(DMSO)2] methanemonoxide, dppeO;bis(diphenylphosphino)ethanemonoxide). dppmO and dppeO behave as monodentate ligands ,coordinated to the metal through phosphorus atom. The Z=sac or,tsac were prepared by the reaction of one mole [Pd(L)2(Z)2] Complexes of the type with two moles of (Nasac or,Htsac) lignads. Sac or tsac ligands showed of trans-[PdCl2(L)2] a different types of behavior toward palladium, sac bonded with Pd(II) through Nitrogen atom while tsac bonded through sulphure atom. The prepared complexes were characterized by I.R 1H nmr and elemental analysis | ||
| Keywords | ||
| Palladium; phosphine monoxides; saccharine; thiosaccharine liginds | ||
|
Statistics Article View: 113 PDF Download: 70 |
||