مع العضیده الجدیده (II) و النحاس (III) تحضیر وتشخیص معقدات الحدید ٤- امینو انتي بایرایل-ن- داي ثایوكاربامیت ملح الامونیوم

	مع العضیده الجدیده (II) و النحاس (III) تحضیر وتشخیص معقدات الحدید ٤- امینو انتي بایرایل-ن- داي ثایوكاربامیت ملح الامونیوم
Journals kufa for chamical
Article 1, Volume 7, Issue 2, 2011, Pages 84-108
Abstract
A new ligand of ammonium 4-amino antipyriyl -N-dithiocarbamate (APDTC) was prepared by reacting of 4-amino antipyrin (4-AAP) with carbon disulfide (CS2) in the presence of ammonium hydroxide .With this ligand, two metal complexes of Cu(II) and Fe (III) were also synthesized under the established optimum conditions. A number of experimental techniques (such as IR, UV-Vis spectrophotometry, conductometry etc) were used to determine a crucial characterization and determination of the structures of these compounds. The data shows that the both complexes combin in molar ratio(metal ion to ligand) of 1:2 and the stability of the complexes ([Fe( APDTC)Cl]and [Cu(APDTC)Cl] 0.15 respectively by mole ratio method at λmax ×0.76 and 109 × of its109 complexes.T he conductivity and magnetic susceptibility data reveals that the both complexes were non-ionic in DMSO and paramagnetic in their nature the chemical structures of the Fe (III) and Cu (II)complexes were also suggested.
Keywords
chamical

Statistics Article View: 180 PDF Download: 139