- All Journals
- Al-Qadisiyah University
- Basrah University
- Kirkuk University
- Mosul University
- The Iraqi Borad for Medical Specialization
- University of Anbar
- University of Technology
- Al Mustafa University
- Al-Zahraa University for Women
- Alnoor University
- Kunooz University
- Misan University
- Ninevah University
- Tikrit University
- University of Al-Hamdaniya
- University of Kerbala
Infrared, Mid infrared and UV-Visible spectra study Cobalt chloride CoCl2. 6H2O molecule | ||
| Baghdad Science Journal | ||
| Article 1, Volume 14, Issue 3, 2017, Pages 503-508 | ||
| Author | ||
| Khalid Hassan Abed | ||
| Abstract | ||
| IR, MIR, UV – Visible spectra have been studied for Cobalt chloride molecule (CoCl2. 6H2O) compound, In wide range spectra (40000 – 410) cm-1 specially MIR range. Assignment were achieved for the fundamental vibrational bands of (CoCl2 . 6H2O ) to symmetry stretching Ʋ1 (∑^+) Anti – symmetry stretching Ʋ3(∑^+), these bands are non-degenerate , and the bending band is Ʋ2(π) is doubly degenerate thought they have activity in IR and Raman , which explain the weakness in symmetry of this molecule, the fundamental bands for the molecule are centered at the following wave numbers (615, 685, 795, 1115, 1340, 1375, 1616.35, 2091, 2386, 2410, 3364) cm-1 which are corresponding to wave lengths (16260, 14598, 12578, 8968, 7462, 7272, 6186, 4782, 4191, 4149, 2972 ) nm The UV and visible spectra of the shows bands centered at (205.7) nm , (48614) cm-1 due to the electronic transition ( n Ϭ^*) , other band centered at (512) nm, (19531) cm-1 due to (n π^*) electronic transition . | ||
| Keywords | ||
| MIR; Visible spectra have been studied for Cobalt chloride molecule; compound; In wide range spectra; specially MIR range; Assignment were achieved for the fundamental vibrational bands of; to symmetry stretching; these bands are non; degenerate; and the bending band is; which explain the weakness in symmetry of this molecule; the fundamental bands for the molecule are centered at the following wave numbers; which are corresponding to wave lengths; nm The UV and visible spectra of the shows bands centered at; due to the electronic transition; other band centered at; due to | ||
|
Statistics Article View: 21 PDF Download: 5 |
||