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Synthesis and Spectroscopic Identification Some Transitional Element Ions Complexes for 3d Series Derived new Mannich Base of Isatin. | ||
| Journal of University of Anbar for Pure Science | ||
| Article 8, Volume 10, Issue 1, 2016, Pages 26-33 PDF (826.76 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2016.132433 | ||
| Author | ||
| Araf Ismael Jabbar* | ||
| Ministry of Education - Anbar Education Directorate | ||
| Abstract | ||
| The present work includes preparation and spectral study of some transition metal complexes of Mn,Co,Ni,Cu(II)and Zn(II)with new Mannich base Z-1-(3-methoxy phenyl amines)methl-3-(p-tolyl)indolin-2-one that behaved as donating bi dentate Lewis base via nitrogen and oxygen atoms .The new Mannich base (L)was prepared in tow step , the first is condensation of indol -2,3-dion with 4-methylaniline ,and the second followed the reachion with formaldehyde and m-anisidine.All the complexes and the Ligand have identified on the basis of C.H.N.elemental analyses , flume atomic absorption ,NMR,IR,Uv- visible ,mass spectra. Furthermore the magnetic moment by Fardy method and molar conductivity measurement in DMF solvent revealed the tetrahedral geometry of [MLCl2].n H2O formal ,n= 1,2,for Co,Ni,Cu+2 . | ||
| References | ||
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