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Synthesis and Spectroscopic Study for Pt (IV) Complexes with 4-Aminoantipyrine and Sodium Pyrophosphate | ||
| Iraqi Journal of Science | ||
| Article 1, Volume 58, Issue 4, 2018, Pages 1985-1997 | ||
| Authors | ||
| Sajid M. Lateef; Sattar R. Majeed; Hanaa A. Mohammed | ||
| Abstract | ||
| Pt (IV) complexes were synthesized from 4-Aminoantipyrine (4-AAP) as a primary ligand, and sodium pyrophosphate as a secondary ligand using metal: ligand in (1:1) mole ratio with molecular formula [Pt (4-AAP)Cl4],[Pt (4-AAP)(Pyph)Cl2]. These complexes were characterized by elemental microanalysis (C.H.N), (A.A), [I.R, (U.V–Vis), mass spectroscopy], along with molar conductivity, chloride contents and melting point measurements. The ligands (4-AAP) and (Pyph) gave octahedral geometry with Pt (IV) rapid, simple, sensitive and validated spectrophotometric method has been described for the determination of platinum (IV) using 4-aminoantipyrine. The complex product was quantitatively measured at 385nm and the reaction conditions were studied and optimized. | ||
| Keywords | ||
| Platinum complex; aminoantipyrine; Sodium pyrophosphate; Spectrophotometry | ||
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