Bariz Omar Ali, A. (2017). Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II). , 28(2), 48-54.
Al-Ameen Bariz Omar Ali. "Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)". , 28, 2, 2017, 48-54.
Bariz Omar Ali, A. (2017). 'Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)', , 28(2), pp. 48-54.
Bariz Omar Ali, A. Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II). , 2017; 28(2): 48-54.

Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)

Al-Mustansiriyah Journal of Science
Article 1, Volume 28, Issue 2, 2017, Pages 48-54
Author
Al-Ameen Bariz Omar Ali
Abstract
Cyclohexane-1,2-bis(thiosemicarbazone) (CHTSC) was synthesized via the condensation reaction
of cyclohexane-1,2-dione and thiosemicarbazide. Series of metal complexes of the prepared ligand,
of general formula [M(CHTSC)(NO3)2], were reported. The prepared coordination complexes
were characterized and their structures elucidated using different techniques. These showed
that all complexes are octahedral geometries. The kinetics of the formation of these complexes
have been investigated using stopped-flow spectrophotometry. These studies revealed that the
reactions are completed on the second’s timescale with 1st-order dependence (either on the concentration
of metal salt or on the concentration of CHTSC)
Keywords
Schiff base ligands; thiosemicarbazones; Kinetic study
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