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Synthesis and Characterization of New Silver (I) N- Heterocyclic Carbene Complex Derived from Imidazol-2- ylidene salt | ||
| Al-Mustansiriyah Journal of Science | ||
| Article 1, Volume 28, Issue 2, 2017, Pages 55-63 | ||
| Author | ||
| Mohammed Mujbel Hasson | ||
| Abstract | ||
| A new N, N'-imidazolium salt 1-(2,6-diisopropylphenyl)-3- (4,6-dimorpholino -1,3,5-traizine-2- yl)-1H-imidazol-3-ium chloride) as a precursor of N - heterocyclic carbene ligand was prepared via the reaction of 1 - (2, 6 - diisopropyl phenyl - 1H - imidazole) with 1, 3, 5 - triazine derivative bearing morpholine substituent (2, 6 -dimorpholine - 6- chloro-1, 3, 5-triaziazine). Linear coordinated Ag (І) NHC complex was synthesised via deprotonation of the imidazolium salt and reaction with Ag2O in darkness at room temperature by in situ method. The complex was synthesised for using as transfer agent to prepare another transition metals complexes by transmetallation method in the future. The imidazolium salt and their silver complex have been characterized by 1 H and 13C NMR spectroscopy as well as mass spectrometry | ||
| Keywords | ||
| Heterocyclic carbene; Silver complexes | ||
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