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Synthesis Structural and Spectroscopic Study for Pd (II) complexes with 4-aminoantipyrine and Sodium pyrophosphate. | ||
| Journal of University of Anbar for Pure Science | ||
| Article 14, Volume 11, Issue 3, 2017, Pages 54-62 PDF (620.85 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2017.145548 | ||
| Authors | ||
| Sajid M. Lateef1; Sattar R. Majeed2; Hanaa A. Mohammed* 2 | ||
| 1College of Education for Pure Science (Ibn Al-Haitham), University of Baghdad, Baghdad, Iraq | ||
| 2College of Science, University of Anbar, Ramadi, Anbar, Iraq | ||
| Abstract | ||
| Pd (II) complexes were synthesized from 4-Aminoantipyrine (4-AAP) as primary ligand, and disodium pyrophosphato as secondary ligands using metal: ligand in (1:1) mole ratio with molecular formula [Pd(4-AAP)Cl2],[Pd(4-AAP) (Pyph)]. These complexes were characterized by elemental microanalysis (C.H.N), (A.A), [I.R, (U.V–Vis), mass spectroscopy], along with molar conductivity, Chloride contents and melting point measurements. The ligands (4-AAP) and (Pyph) gave square planar geometrical formula with Pd (II). Rapid, simple, sensitive and validated spectrophotometric method has been described for the determination of palladium (II) using 4-aminoantipyrine. The complex product was quantitatively measured at 363nm and the reaction conditions were studied and optimized. | ||
| Keywords | ||
| synthesis; Structural; Spectroscopic; complexes; aminoantipyrine; Sodium pyrophosphate | ||
| References | ||
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