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SYNTHESIS AND CHARACTERIZATION OF IRON(II), COBALT(II), NICKEL(II), COPPER(II), AND ZINC(II) COMPLEXES USING DIPHENYLMETHYL XANTHATE LIGAND | ||
| ARO-THE SCIENTIFIC JOURNAL OF KOYA UNIVERSITY | ||
| Article 5, Volume 6, Issue 1, 2018, Pages 33-37 PDF (506.57 K) | ||
| DOI: 10.14500/aro.10243 | ||
| Authors | ||
| Aeed S. Al-Fahdawi; Eman I. Alsalihi | ||
| Abstract | ||
| Potassium Diphenylmethyl Xanthate and its monomeric complexes were synthesized at room temperature under inert gas and stirring condition. The ligand and its complexes of the general formula [M(L)2] (where M= FeII, CoII, NiII , CuII, ZnII and CdII) were characterized by spectroscopic methods (IR, UV-Vis, 1H-, 13C-, DEPT-, HQMC- and COSY-NMR), elemental analysis, metal content, magnetic susceptibility measurement and molar conductance. These studies revealed the formation of four coordinate complexes. | ||
| Keywords | ||
| Four-coordinate complexes; Potassium diphenylmethyl xanthate ligand; Structural study; Xanthate complexes | ||
| References | ||
|
Al-Fahdawi, A.S. and Al-Salihi, I.I., 2015. Preparation of Tris (diphenyl. methanol) binding by hydrogen bonds through the application of microwave. techniques. International Journal of Current Research in Biosciences and Plant Biology, 2(7), pp.1-9.
Al-Fahdawi, A.S., Al-Kafajy, H.A., Al-Jeboori, M.J. and Potgieter, H., 2014. New bimetallic bisdithiocarbameta-based macrocyclic complex; Preparation and spectral characterization. ChemXpress, 4(3), pp.262-267.
Al-Fahdawi, A.S., Al-Kafajy, H.A., Al-Jeboori, M.J. and Potgieter, H., 2013. Synthesis, spectral and structural studies of neutral co(II), Ni(II) and Cu(II)macrocyclic dithiocarbamate- based complexes formed via one pot reaction. Iraq National Journal of Chemistry, 52, pp.414-429.
Aly, M.M., Baghlaf, A.O. and Ganji, N.S., 1985. Linkage isomerism of the oximato group: The characterization of some mono- and binuclear square planar nickel(II) complexes of vicinal oxime-imine ligands. Polyhedron, 4, pp.1301.
Batten, S.R. and Robson, R., 1998. Interpenetrating nets: Ordered, periodic entanglement. Angewandte Chemie International Edition, 37, pp.1460-1494.
Batten, S.R., 2001. Topology of interpenetration. Cryst Eng Commy, 22, pp.67-72.
Beer, P.D., Cowley, A.R., Jeffery, J.C., Paul, R.L. and Wong, W.W. H., 2003.
Self-assembled xanthate-transition metal polyether macrocycles and cryptands. Polyhedron, 22(5), pp.795-801.
Carlucci, L., Ciani, G. and Proserpio, D.M., 2003. Polycatenation, polythreading and polyknotting in coordination network chemistry. Coordination Chemistry Reviews, 246, pp.246-247.
Coucouvanis, D., 1979. Progress in Inorganic Chemistry. Vol. 26. John Wiley, New York. pp.302.
Cox, M.J. and Tiekink, E.R.T. 1996. Stnthises and characterization of arylxanthates of group 12th elements. Kristallog. 211, pp.111-113.
Dokken, K.M., Parsons, J.G., McClure, J. and Gardea-Torresdey, J.L., 2009.
Synthesis and structural analysis of copper(II) cysteine complexes. Inorganica Chimica Acta, 362, pp.395-401.
Exarchos, G., Robinson, S. and Steed, J., 2001. Should solid-state molecular packing have to obey the rules of crystallographic symmetry. Polyhedron, 20, pp.2951.
Griffith, D.M., Szocs, B., Keogh, T., Suponitsky, K.Y., Farkas, E., Buglyo, P. and Marmion, C.J., 2011. Suberoylanilide hydroxamic acid, a potent histonedeacetylase inhibitor: Its X-ray crystal structure and solid state and solution studies of its Zn(II), Ni(II), Cu(II) and Fe(III) complexes. Journal of Inorganic Biochemistry, 105, pp.763-769.
Guillemet-Fritsch, S., Lebey, T., Boulos, M. and Durand, B., 2006. Dielectric properties of CaCu3Ti4O12 based multiphased ceramics. Journal of the European Ceramic Society, 26, pp.1245-1257.
Gurpreet, K., Inderjeet, K. and Renu, S., 2013. Synthesis and characterization of the adducts of bis(O-ethyldithiocarbonato) copper(II) with substituted pyridines. International Journal of Inorganic Chemistry, 2013, pp.502856.
Kavitha, N. and Lakshm, P.V.A., 2017. Synthesis, characterization and thermogravimetric analysis of Co(II), Ni(II), Cu(II) and Zn(II) complexes supported by ONNO tetradentdate Schiff base ligand derived from hydrazine benzoxazine. Journal of Saudi Chemical Society, 21, pp.S457-S466.
Kour, G. Kour, I. and Sachar, R. 2013. Synthesis and characterization of the adducts of bis(O-ethyldithiocarbonato)copper(II) with substituted pyridines. International Journal of Inorganic Chemistry, 2013, pp.502856.
Lever, A.B.P., 1984. Inorganic Electronic Spectroscopy. Elsevier Publishing, NewYork.
Ma, Q., Zhu, M., Lu, L., Feng, S. and Ya, J., 2011. Preparation of molecularly imprinted polymer and its recognition property for salvianolic acid A. Chimica Acta, 370, pp.102-107.
Rao, S.R., 1971. Xanthates and related compounds. Marcel Dekker, New York.
Seleem, H.S., El-Inany, G.A., El-Shetary, B.A. and Mousa, M.A., 2011. The ligational behavior of a phenolic quinolyl hydrazone towards copper (II)-ions. Chemistry Central Journal, 5, pp.2.
Srinivasan, S., Ramalingam, K. and Rizzoli, C., 2012. Synthesis, NMR and single crystal X-ray structural studies on planar NiS4 and NiS2PN chromophores: Steric and electronic effects. Polyhedron, 33, pp.60-66.
Vastag, S., Marko, L., Rheingold, A.L.J. 1990. Pentacoordinate cobalt(III) thiolate and nitrosyl tropocoronand compounds. Organometallic Chemistry, 397, pp.231.
Yu, K., Gu, Z., Ji, R. and Lou, L.S., 2009. Mild oxidation of alkanes and toluene by tert-butylhydroperoxide catalyzed by an homogeneous and immobilized Mn(salen) complex. Tetrahedron, 65, pp.305-311.
Zelenak, V. and Gyoryov, K.D., 2002. Correlation of infrared spectra of zinc (II) carboxylates with their structures. Spectrochim Acta, 8, pp.269.
Zheng, Z., Junwei, X., Sisi, Y., Yangli, C., Yan, W., Zhuo, C. and Chunlin, N., 2017. Two organic cation salts containing tetra(isothiocyanate)cobaltate(II): Synthesis, crystal structures, spectroscopic, optical and magnetic properties. Crystals, 7, pp.92.
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