M. F. AL-HEETY, M. (2012). SYNTHESIS OF SOME DERIVATIVES 9-ARYL-1,8-DIOXOOCTAHYDROXANTHENE AND 2,2’-ARYL-METHYLENE BIS(3-HYDROXY-2-CYCLOHEXENE-1-ONE) IN AQUEOUS MEDIA. , 1(3), 45-51. doi: 10.37652/juaps.2007.15597
MARWAN M. F. AL-HEETY. "SYNTHESIS OF SOME DERIVATIVES 9-ARYL-1,8-DIOXOOCTAHYDROXANTHENE AND 2,2’-ARYL-METHYLENE BIS(3-HYDROXY-2-CYCLOHEXENE-1-ONE) IN AQUEOUS MEDIA". , 1, 3, 2012, 45-51. doi: 10.37652/juaps.2007.15597
M. F. AL-HEETY, M. (2012). 'SYNTHESIS OF SOME DERIVATIVES 9-ARYL-1,8-DIOXOOCTAHYDROXANTHENE AND 2,2’-ARYL-METHYLENE BIS(3-HYDROXY-2-CYCLOHEXENE-1-ONE) IN AQUEOUS MEDIA', , 1(3), pp. 45-51. doi: 10.37652/juaps.2007.15597
M. F. AL-HEETY, M. SYNTHESIS OF SOME DERIVATIVES 9-ARYL-1,8-DIOXOOCTAHYDROXANTHENE AND 2,2’-ARYL-METHYLENE BIS(3-HYDROXY-2-CYCLOHEXENE-1-ONE) IN AQUEOUS MEDIA. , 2012; 1(3): 45-51. doi: 10.37652/juaps.2007.15597

SYNTHESIS OF SOME DERIVATIVES 9-ARYL-1,8-DIOXOOCTAHYDROXANTHENE AND 2,2’-ARYL-METHYLENE BIS(3-HYDROXY-2-CYCLOHEXENE-1-ONE) IN AQUEOUS MEDIA

Journal of University of Anbar for Pure Science
Article 12, Volume 1, Issue 3, 2007, Pages 45-51    PDF (413.16 K)
Document Type: Research Paper
DOI: 10.37652/juaps.2007.15597
Author
MARWAN M. F. AL-HEETY*
Anbar University - Department of Chemistry - College of EducationAnbar
Abstract
This research concerned with the reaction of Aryl- benzoylchloride with 1,3-cyclohexanedione in aqueous media (which has been catalyzed by p-dodecylbenezenesulfonic acid (DBSA) or sodiumdodecylsulfate (SDS)). The product include two types derivatives : seven compounds from 9-aryl-1, 8-dioxooctahydroxanthene derivatives and seven compounds from 2,2’-arylmethylene Bis-(3- hydroxy- 2-cyclohexene-1-one) derivatives. The Products were diagnosed by the spectral methods (I.R.) and the elements quantities analyses(C.H.N.). Add-on products compound's, This method provides several advantages such as good yield, simple work-up procedure and environment friendly
Keywords
aryl; dioxooctahydroxanthene; methylene bis; hydroxy; cyclohexene; One; aqueous media
References
  1. Foye W.O. Prinicipi di Chimica Farmaceutica Piccin, Padova, Italy, 1991, 416. (b) Andreani L L, Lapi E Boll. Chim. Farm. 1960, 99, 583.  (c) Chem. Abstr., 1982, 96, 135383e (d) Bonsignore L, Loy G, Secci D and Calignano A, Eur. J. Med.Chem. 1993, 28, 517. (e) Chem. Abstr., 1986, 104, 224915f..
  2. Hatakeyama S, Ochi N, Numata H and Takano S, J. Chem. Soc. Chem. Commun 1988, 1202. (b) Cingolant G M and Pigini M, J. Med. Chem. 1969, 12, 531.
  3. Li C.J and Chan T.H, Organic reactions in aqueous media, Wiley, New York, 1997.
  4. Ellis G.P., The chemistry of Heterocyclic compounds. In chromenes, chromanes and Chromeones, Weissberger A and Taylor E C, New York, 1977, p 13.
  5. Hafez E.A, Elnagdi M.H, Elagamey A.A and El-Taweel F.A M, Heterocycles 1987, 26, 903. (b) Abdel Galil F M, Riad B Y, Sherif S M and Elnagdi M H, Chem.Lett. 1982, 1123.
Anastas P and Williamson T, Green Chemistry, Frontiers in Benign ChemicalSynthesis and Procedures, Oxford Science Publications, 1998

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