RAJAB HABEEB, A. (2012). SYNTHESIS AND CHARACTERIZATION OF MIXED LIGANDS COMPLEXES OF IMIDAZOL AND NAPHTHAL HYDROXAMIC ACID WITH MN(II), FE(II), CO(II), NI(II) AND CU(II). , 4(3), 28-32. doi: 10.37652/juaps.2010.15652
ABDULHADII RAJAB HABEEB. "SYNTHESIS AND CHARACTERIZATION OF MIXED LIGANDS COMPLEXES OF IMIDAZOL AND NAPHTHAL HYDROXAMIC ACID WITH MN(II), FE(II), CO(II), NI(II) AND CU(II)". , 4, 3, 2012, 28-32. doi: 10.37652/juaps.2010.15652
RAJAB HABEEB, A. (2012). 'SYNTHESIS AND CHARACTERIZATION OF MIXED LIGANDS COMPLEXES OF IMIDAZOL AND NAPHTHAL HYDROXAMIC ACID WITH MN(II), FE(II), CO(II), NI(II) AND CU(II)', , 4(3), pp. 28-32. doi: 10.37652/juaps.2010.15652
RAJAB HABEEB, A. SYNTHESIS AND CHARACTERIZATION OF MIXED LIGANDS COMPLEXES OF IMIDAZOL AND NAPHTHAL HYDROXAMIC ACID WITH MN(II), FE(II), CO(II), NI(II) AND CU(II). , 2012; 4(3): 28-32. doi: 10.37652/juaps.2010.15652

SYNTHESIS AND CHARACTERIZATION OF MIXED LIGANDS COMPLEXES OF IMIDAZOL AND NAPHTHAL HYDROXAMIC ACID WITH MN(II), FE(II), CO(II), NI(II) AND CU(II)

Journal of University of Anbar for Pure Science
Article 8, Volume 4, Issue 3, 2010, Pages 28-32    PDF (441.1 K)
Document Type: Research Paper
DOI: 10.37652/juaps.2010.15652
Author
ABDULHADII RAJAB HABEEB*
Ministry of Higher Education and Scientific Research
Abstract
ABSTRACT:The mixed ligands complexes of Imidazol (Im) and naphthal hydroxamic acid (NHA) with
transition metal salt of Mn(II), Fe(II), Co(II), Ni(II) and Cu(II) were prepared . they were characterized by
using (FT-IR) spectroscopy,(UV-Vis.) spectrophotometery and chlorine content test, atomic absorption
spectroscopy also by using molar conductance . this study showed that ligand Imedazol behaves as a
monodentate ligand and Naphthalhydroxamic acid as a chelating tridentate ligand , the complexes have an
octahedral geometry. The free ligands and their complexes have been tested for their antibacterial
activities against four kinds of human pathogenic bacteria: (Streptococcus paecalies, Staphylococcus
aureus), (Escherichia coli, Klebsiella Peneumonia ). the first group are Gram positive while the second
group are Gram negative by using agar well diffusion method. Finally ,it was found that compounds show
different activity of inhibition on growth of the bacteria
References

 

  1. Zuhoor  F.D.  and  Al – Shamaa  M. , Al – Taqani , Vol. 19 , No. 1 , PP. 23-32  ( 2006 ) .
  2. Mostava  M.M. , Shallaby  A.M.  and  El – Asmy.  A.A. , J. Inorg. Nucl. Chem. , 43 , P. 292  , (1981) .
  3.  Kowol  C.R., Berger  R. , Eichinger   R. , Roller   A. , Jakupec M. A.  , Schmidt  P.P. ,    
  4. Arion  V.B.  and   Keppler  B.K. , J. Med Chem. , 50 ( 6 ) , PP.  1254 – 1265  ( 2007 ) .
  5. Wilson and Givold," Text book of organic Medical and Pharmacology Chemistry", 8th ed, 107 (1982).
  6. Alessandro, B., Clara, C., Giaframco, S., J. Am. Chem. Soc., 116,916 (1994).
  7. Biliana,N., Kujundzie,N., Sancovic., Acta. Chem. Solv., 49,525(2002).
  8. Neilands,J.B., J.Biol.Chem., 270,26723(1995).
  9. Tudor R., Aurelian  G., Nicolae  A. and  Georgescu  R. , J.Molecules , 12 , PP.  782 – 790  (2007) . 
  10. 10.   Casas  J.J. , Garsia  M.S.  and  Sordo  J. , Coord. Chem. Rev. ,197 , P. 209(2000) .
  11. 11.  Ferruti,P.,Bettelli,A., J.Polymer., 13,462(1972).
  12. 12.  Silverstein, R.M., Bassler,  G.C. and Movril,T.C., 1981, "Spectroscopic Identification of organic  compounds", New York, Wiley.
  13. 13.  Raman, N., S. Ravichandran, and Thangaraja, c., (2004)., J.Chem.Soc.,11:4.PP(215-219).
14. Kirchner,R.M., Mealli, M. Baily, N. House, L.P. Torrel, and Lingafelter, E.C.(1987).," The      

15. variable coordination chemistry of transition metal ions "., Coord. Chem. Rev., 77. Pp (153-163).

  1. 16.  Nakamoto,N. (1966), "Infrared Spectra of Inorganic Coordination compounds"., 4th, Ed. Wiley  Inter science New York.
  2. 17.  Bellamy,L.J.(1978)., "The infrared spectra of complex Molecules"., Chapman and Hall. London.
  3. 18.  Figgis, B.N.,(1966). "Introduction to ligand field"., inter science publisher inc. New York.
  4. 19.  Lever, A.B. (1986).," Inorganic Electronic spectroscopy"., Amsterdam-London, New York.
20. Ghosh T. , Roy A. , Bhattacharya S. and Banerjee S., Trans. Metal.Chem., 30(4 , PP. 419-425 (2005).

  1. 21.  Rajavel,R., Vadiva, M.S. and Anltha, C. (2008). " synthesis , spectral characterization and   
22. biological activity of some Schiff base compounds.", E.J. of Chem. ,5: 30. Pp( 620-626).

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