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complexes of Schiff's basis drivered from amino acids to acetylfuorine with their biological activity | ||
| Journal of Education and Science | ||
| Article 16, Volume 27, Issue 4, 2018, Pages 67-83 PDF (0 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.33899/edusj.2018.159287 | ||
| Authors | ||
| thanaa Yosif; Hibaa Al-Kateeb | ||
| Abstract | ||
| A new complexes of some transition metal ions (Co(II),Ni(II),Cu(II)) and non-transition metal ions (Zn(II),Cd(II)) with a number of Schiff bases obtained from the condensation of some amino acids isoleucine, phenylalanine and alanine with (2-acetylfuran) have been prepared. All the prepared complexes have been characterized by elemental analysis(M), molar conductance, magnetic susceptibility infrared and electronic spectral. The complexes were classified as: A-mononuclear complexes. 1-Complexes with the formulas [ML(CH3COO) (H2O)2]. 2- Complexes with the formulas [ML(CH3COO) ] H2O. B-Homo dinuclear complexes. Complexes with the formulas [M2(L)2(CH3COO)2] .2H2O. M= Co(II),Ni(II),Cu(II),Zn(II)Cd(II). L= 2-Acetyl furan isoleucine imine, 2-Acetyl furan phenylalanine imine and 2-Acetyl furan alanine imine. The physical measurements showed that the prepared complexes have a tetra coordinated (tetrahedral) and hexa-coordinated (octahedral) structure and that all the prepared complexes were non electrolyte. | ||
| Keywords | ||
| Schiff bases; tow acetylfuorine; biological activity | ||
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