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Preparation and Characterization of some Transition Metal Complexes with OleylXanthate and 1,10- Phenanthrolin | ||
| Rafidain Journal of Science | ||
| Article 24, Volume 28, Issue 2, 2019, Pages 228-234 PDF (517.36 K) | ||
| DOI: 10.33899/rjs.2019.159987 | ||
| Authors | ||
| Fayhaa K. AL-Jarah* ; Saad E. AL-Mukhtar | ||
| Abstract | ||
| Xanthatecomplexes of the general formula [M{Ag(oleylXant)2}2] (A) and [MM'(oleylXant)4] (B) were M = Copper (II), Nickel II), Cobalt (II) M' = Cadmium(II), Zinc(II). These complexes were reacted with bidentatelewis base (1,10-phenanthroline). The result of this reaction gave the complexes [M(phen)][{Ag(oleylxant)2}2] (I.A) and [M(phen)][M'(oleyl-xant)4] (I.B), which have been prepared and measured by an infrared, magnetic suscetptibility measurements, conductance measurements, electronic spectra and elemental analysis electronic absorption spectra. These data indicate gave the result that the complexes of the type (A & B) are a square planer geometry while the complexes of the type (I.A), (I.B) have an octahedral geometry. . | ||
| Keywords | ||
| Square wave voltammetry; Xanthate; cobalt; Valsartan; Glibenclamide; nickel; copper; Drug interaction; Phenanthroline | ||
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