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The Influence of pH and Temperature on Tautomerism Reactions of Some Aromatic Mono and Bi Schiff Bases | ||
| Iraqi National Journal Of Chemistry | ||
| Article 1, Volume 0, Issue 26, 2014, Pages 295-304 | ||
| Authors | ||
| A.B.N. Al-Dabagh; | ||
| Abstract | ||
| Abstract The aims at investigation the tautomerism reaction of mono and bi aromatic Schiff bases by actions of different values of pH,s and temperatures. The pH under study was chosen in a range between 4-10. Experiments prove the existence of Schiff bases under study, as tautomeric equilibrium mixture of different ratios of keto and enol forms , as well as , the formations of nitrilium and phenoxonium ions in acidic and basic media respectively. Equilibrium constants K for the tautomerism reaction are evaluated at a temperature range between 298-338k. the last shows an inverse relationship between K and T which facilitates the evaluation of thermodynamic parameters. Finally evidence for supporting the tautomerism reaction is mentioned and disussed. | ||
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