S. Al-Dulaimi, J., I.Abdulkarim, E., Jaber Al-Jeboori, M. (2007). New six coordinate cobalt(III) complexes of [1,2-diaminoethane –N,Ń-bis (2-butylidine -3-onedioxime)]. , 0(26), 331-341.
Jassim S. Al-Dulaimi; Eman I.Abdulkarim; Mohamad Jaber Al-Jeboori. "New six coordinate cobalt(III) complexes of [1,2-diaminoethane –N,Ń-bis (2-butylidine -3-onedioxime)]". , 0, 26, 2007, 331-341.
S. Al-Dulaimi, J., I.Abdulkarim, E., Jaber Al-Jeboori, M. (2007). 'New six coordinate cobalt(III) complexes of [1,2-diaminoethane –N,Ń-bis (2-butylidine -3-onedioxime)]', , 0(26), pp. 331-341.
S. Al-Dulaimi, J., I.Abdulkarim, E., Jaber Al-Jeboori, M. New six coordinate cobalt(III) complexes of [1,2-diaminoethane –N,Ń-bis (2-butylidine -3-onedioxime)]. , 2007; 0(26): 331-341.

New six coordinate cobalt(III) complexes of [1,2-diaminoethane –N,Ń-bis (2-butylidine -3-onedioxime)]

Iraqi National Journal Of Chemistry
Article 1, Volume 0, Issue 26, 2014, Pages 331-341
Authors
Jassim S. Al-Dulaimi; Eman I.Abdulkarim; Mohamad Jaber Al-Jeboori
Abstract
Abstract
The ligand [1,2-diaminoethane –N,Ń-bis (2-butylidine -3-onedioxime)][H2L]. was reacted with Co(NO3)2.6H2O and KBr in ethanol with reflux in (1:1) metal : ligand ratio to give a new complex of the general formula [CoIII(HL)Br2]. A series of new complexes with some heterocyclic nitrogen and aliphatic amine ligands of the general formula [CoIII(HL)(X)Br]Br (where: X=pyridine, 4-picoline, and 3-picoline, piperidine, octylamine, n-propylamine and Br) were prepared. All compounds have been characterised by spectroscopic methods [IR, U.V-Vis, atomic absorption, (1H NMR, and EI-mass spectroscopy for the ligand)], microanalysis andwith conductivity measurements. From the obtained data, a distorted octahedral molecular structure about Co(III) ion has been proposed.
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