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Synthesis and Characterization of Pd(II) And Pt(II) Complexes with Bis [Hg (2-Apt)] Compound. | ||
| Kirkuk Journal of Science | ||
| Article 1, Volume 13, Issue 3, 2018, Pages 12-22 PDF (0 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.32894/kujss.2018.13.3.2 | ||
| Authors | ||
| Beriwan Mohamad Hamad Ameen* ; Hikmat Ali Mohamad | ||
| Department of Chemistry, College of Education, Salahaddin University, Erbil, Iraq. | ||
| Abstract | ||
| The reaction of one mole of Hg(II) acetate with two mole of 2-amino thiophenol gave one mole of [Hg(2-apt)] compound. While the reaction of one mole of [Hg(2-apt)] with two moles of MCL2 salt. Produced new complexes in general formula [M2{Hg(2-apt)Cl4] where M=Pt(II) or Pd(II).All the prepared complexes were identified using FT-IR, 1H-NMR,13C-NMR,elemental analyses (CHNS) and molar conductivity. The results exhibited that metal bounded to the ligand via S and N in squar planer geometries.. | ||
| Keywords | ||
| bis; apt; and Pt; Spectral data | ||
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