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The Influence of pH and Temperature on Tautomerism of Imines Derived from 2-hydroxy -1- napthaldehyde . | ||
| Iraqi National Journal Of Chemistry | ||
| Article 1, Volume 0, Issue 20, 2014, Pages 568-585 | ||
| Authors | ||
| ; A.A. Rahman; | ||
| Abstract | ||
| Abstract The tautomerism reactions of one oxime molecule and seven Schiff bases derived from 2- hydroxy-1- napthaldehyde with an appropriate aliphatic and aromatic amines were studied . The study is mainly concerned with the tautomerism reactions of the above mentioned imines . This requires the measurements of UV absorption spectra of imines 2-9 under the influence of different pH values in the range 4-10 and different temperatures. This is accomplished by the evaluation of equilibrium constants K1 and K2 for the tautomerism and isomerization reactions respectively and for imines 3-7 The remaining imines 2,8 and 9 undergo a tautomerism reaction only . The result shows that the extent of keto and enol forms in these imines are altered by the variation of both , pH and temperature . The processes of tautomerism and isomerization reactions are proved by the evaluation of thermodynamic parameters which were measured in ethanol and 1,2- dichloroethane . The ΔH values calculated for both reactions indicate an exothermic reactions type.Also these reactions being either spontaneous or nonspontaneous as confirmed from the sign and value of ΔG estimated .Finally the calculated negative entropies values ΔS , support these reactions stated above and are accompanied by loss of keto entropy .Finally , a suitable explaination for the last behavior is given and discussed . | ||
| Keywords | ||
| Tautomerism and isomerization reactions; UV study; thermodynamic of tautomerism; thermodynamic of isomerization; Schiff Base; Oxime | ||
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