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Synthesis, spectral Characterization and studies of Some Divalent Metal Ion Complexes with Ligand of [3-(1H-indol-3-yl)-2-(3-(4-methoxybenzoyl)thiouereido)propanoic acid] (MTP) | ||
| Journal of University of Anbar for Pure Science | ||
| Article 7, Volume 12, Issue 1, 2018, Pages 28-37 PDF (736.32 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2022.171467 | ||
| Authors | ||
| Basima M. Sarhan1; Sattar S. Ibrahem2; Abdulsattar Z. Khalaf* 2 | ||
| 1Dept. of Chemistry, College of Education for Pure Science (Ibn Al-Haitham), University of Baghdad | ||
| 2Dept. of Chemistry, College of Science, University of Anbar | ||
| Abstract | ||
| In this work, prepared new ligand[3- (1H-indol-3-yl) -2- (3-(4-methoxybenzoyl)thiouereido) propanoic acid](MTP) has been synthesized by reaction of 4-Methoxybenzoyl isothiocyanate with tryptophane(1:1), The ligand was characterized by elemental microanalysis C.H.N.S, FT-IR, UV-Vis and 1H,13C NMR spectra, Some transition metals complexes of this ligand were prepared and characterized by FT-IR, UV-Vis spectra, conductivity measurements, magnetic susceptibility and atomic absorption, From obtained results the molecular formula of all prepared complexes were [M(MTP)2] (M+2 =Mn, Co, Ni, Cu, Zn, Cd and Hg), the proposed geometrical structure for all complexes were tetrahedral except copper complex has a square planer geometry around metallic ion with bidentate ligand(MTP). | ||
| Keywords | ||
| tryptophan; 4-Methoxybenzoylisothiocyanate; Divalent metal ion; complexes | ||
| References | ||
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