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Synthesis and Characterization of new 3-(2-(6-oxo-1,3-thiazinan-3-yl)-R)-1,3-oxazepane-4,7-dione and N-Bromo Amines 1,3-oxazepane-4,7-dione Derivatives. | ||
| Journal of University of Anbar for Pure Science | ||
| Article 14, Volume 12, Issue 1, 2018, Pages 66-74 PDF (574.12 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2022.171572 | ||
| Authors | ||
| Walid Faraj AL-Hiti* 1; Safa Abdulsalam Abdalgabar2 | ||
| 1Chemistry Department, Education College for women, Al-Anbar University, Anbar, IRAQ | ||
| 2Chemistry Department, Science College, Al-Anbar University, Anbar, IRAQ | ||
| Abstract | ||
| This study includes synthesis and characterization of new derivatives of 3-(2-(6-oxo-1,3-thiazinan-3-yl)-R)-1,3-oxazepane-4,7-dione and N-Bromo amines 1,3-oxazepane-4,7-dione derivatives. Schiff's bases reactions through one step process in inert solvents. Some employing Schiff's bases [1- 4]; in addition, synthesized by the reaction of different amines with (Salicylaldehyde) in absolute ethanol under reflux. Heterocyclic rings of 1,3-oxazepane-4,7-dione prepared by the reaction of succinic anhydride with Schiff's bases [1-4] and 3-(2-(6-oxo-1,3-thiazinan-3-yl)-R)-1,3-oxazepane-4,7-dione derivatives were prepared by the reaction of 3-mercaptopropanoic acid with 1,3-oxazepane-4,7-dione[A1-A4] in 1,4-dioxan. Synthesis of some N-bromo amine derivatives by the reaction of 1,3-oxazepane-4,7-dione[A1-A4] with 2,4,4,6-TBCD (2,4,4,6-tetrabromocyclohexa-2,5-dienone) in dry benzene; The prepared compounds were identified by melting point, FT-IR, UV-Vis and 1H- NMR spectroscopy. | ||
| Keywords | ||
| This study includes synthesis and characterization of new derivatives of 3-; 7-dione and N-Bromo amines 1; 7-dione derivatives. Schiff's bases reactions through one step process in inert solvents. Some employing Schiff's bases [1- 4]; in addition; synthesized by the reaction of different amines with; Salicylaldehyde in absolute ethanol under reflux. Heterocyclic rings of 1; 7-dione prepared by the reaction of succinic anhydride with Schiff's bases [1-4] and 3-; 2-; 6-oxo-1; 3-thiazinan-3-yl-R-1; 7-dione derivatives were prepared by the reaction of 3-mercaptopropanoic acid with 1; 7-dione[A1-A4] in 1; 4-dioxan. Synthesis of some N-bromo amine derivatives by the reaction of 1; 3-oxazepane-4; 7-dione[A1-A4] with 2; 6-TBCD; 2; 4; 6-tetrabromocyclohexa-2; 5-dienone in dry benzene; The prepared compounds were identified by melting point; FT-IR; UV-Vis and 1H- NMR spectroscopy | ||
| References | ||
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