Hydrodeoxygenation of linoleic acid using water as hydrogen source on Co/HB zeolite

Alqazweeny, Fouz D; Jazie, Ali A.

doi:10.30772/qjes.2023.143941.1042

	Hydrodeoxygenation of linoleic acid using water as hydrogen source on Co/HB zeolite
Al-Qadisiyah Journal for Engineering Sciences
Article 3, Volume 17, Issue 2, June 2024, Pages 104-109 PDF (644.16 K)
Document Type: Research Paper
DOI: 10.30772/qjes.2023.143941.1042
Authors
Fouz D Alqazweeny; Ali A. Jazie^*
Chemical Engineering Department, College of Engineering, University of Al-Qadisiyah, Al-Diwaniyah City P.O. Box 1767, Iraq
Abstract
Hydrodeoxygenation (HDO) is a critical step in upgrading biomass-derived feedstock to renewable fuels and valuable chemicals. Thus, preserving the environment through the use of agricultural waste. Water plays the role of solvent, reactant, or byproduct in biomass HDO reactions, which are catalyzed by Co/HB zeolite catalysts. In this investigation, The hydrodeoxygenation of linoleic acid was examined in a patch-packed-bed reactor with a beta zeolite range of (5-15) mg and catalyzed at a temperature range of 230-300 K for 2-3 h. Linoleic acid, an unsaturated fatty acid, was used in this work to create hydrocarbons in the diesel range, as well as to clarify the impact of zeolite quantity, temperature, and time on the yielded product, to produce biofuels from Linoleic acid by hydrodeoxygenation in the high-pressure reactor in the presence of the catalyst. The products are then characterized by gas chromatography-mass spectrometry (GC-MS). Based on the optimization results, it was determined that the hydrodeoxygenation reaction primarily eliminated the oxygen atoms from fatty acids. The yield of the intended products was 96.2% at the Co/HB zeolite amount (10% wt), high reaction temperature (270 ºC), and time (150 min) conditions.
Keywords
Bio-fuel; Co/HB zeolite; Deoxygenation; Hydrodeoxygenation; Llinoleic

References
A. Jazie, J. Haydary, S.A. Abed, M.F. Al-Dawody, Hydrothermal liquefaction of Fucus vesiculosus algae catalyzed by Hβ zeolite catalyst for Biocrude oil production, Algal Research, 61 (2022) 102596. https://doi.org/10.1016/j.algal.2021.102596 Martini, J.S. Schell, Plant oils as fuels: present state of science and future developments, Springer Science & Business Media, Berlin, Heidelberg, 2012. https://doi.org/10.1007/978-3-642-72269-1 Monyem, J.H. Van Gerpen, The effect of biodiesel oxidation on engine performance and emissions, Biomass bioenergy, 20 (2001) 317-325. Kubičková, M. Snåre, K. Eränen, P. Mäki-Arvela, and D. Y. Murzin, Hydrocarbons for diesel fuel via decarboxylation of vegetable oils, Catalysis Today, 106 (2005) 197-200. https://doi.org/10.1016/j.cattod.2005.07.188 Şenol, T.-R. Viljava, and A. Krause, Effect of sulphiding agents on the hydrodeoxygenation of aliphatic esters on sulphided catalysts, Applied Catalysis A: General, 326 (2007) 236-244. https://doi.org/10.1016/j.apcata.2007.04.022 Altın, S. Cetinkaya, and H.S. Yücesu, The potential of using vegetable oil fuels as fuel for diesel engines, Energy conversion management, 42 (2001) 529-538. https://doi.org/10.1016/S0196-8904(00)00080-7 Gusmao, D. Brodzki, and G. Djéga-Mariadassou, and R. Frety, Utilization of vegetable oils as an alternative source for diesel-type fuel: hydrocracking on reduced Ni/SiO2 and sulphided Ni-Mo/γ-Al2O3, Catalysis Today, 5 (1989) 533-544. https://doi.org/10.1016/0920-5861(89)80017-3 Nunes, D. Brodzki, G. Bugli, and G. Djéga-Mariadassou, Hydrocracking of soybean oil under pressure: research procedure and general aspects of the reaction, Revue De L Institut Francais Du Petrole, 41 (1986) 421-431. Maher, D. Bressler, Pyrolysis of triglyceride materials for the production of renewable fuels and chemicals, Bioresource technology, 98 (2007) 2351-2368. https://doi.org/10.1016/j.biortech.2006.10.025 J. Nuhma, H. Alias, M. Tahir, and A.A. Jazie, Bimetallic Lanthanum-Cerium-Loaded HZSM-5 Composite for Catalytic Deoxygenation of Microalgae-Hydrolyzed Oil into Green Hydrocarbon Fuels, Molecules, 27 (2022) 8018. https://doi.org/10.3390/molecules27228018 J. Nuhma, H. Alias, and M. Tahir, A.A. Jazie, Ce-Loaded HZSM-5 Composite for Catalytic Deoxygenation of Algal Hydrolyzed Oil into Hydrocarbons and Oxygenated Compounds, Molecules, 27 (2022) 7251. https://doi.org/10.3390/molecules27217251 Dupain, D.J. Costa, C.J. Schaverien, M. Makkee, and J.A. Moulijn, Cracking of a rapeseed vegetable oil under realistic FCC conditions, Applied Catalysis B: Environmental, 72 (2007) 44-61. https://doi.org/10.1016/j.apcatb.2006.10.005 Snare, I. Kubickova, P. Maki-Arvela, K. Eranen, and D.Y. Murzin, Heterogeneous catalytic deoxygenation of stearic acid for production of biodiesel, Industrial Engineering Chemistry Research, 45 (2006) 5708-5715. https://doi.org/10.1021/ie060334i Mäki-Arvela, I. Kubickova, M. Snåre, K. Eränen, and D.Y. Murzin, Catalytic deoxygenation of fatty acids and their derivatives, Energy Fuels, 21 (2007) 30-41. https://doi.org/10.1021/ef060455v A. Bezerra, R.E. Santelli, E.P. Oliveira, L.S. Villar, L.A. Escaleira, Response surface methodology (RSM) as a tool for optimization in analytical chemistry, Talanta, 76 (2008) 965-977. https://doi.org/10.1016/j.talanta.2008.05.019 O. Odude, A.J. Adesina, O.O. Oyetunde, O.O. Adeyemi, N.B. Ishola, A.O. Etim, and E. Betiku, Application of agricultural waste-based catalysts to transesterification of esterified palm kernel oil into biodiesel: A case of banana fruit peel versus cocoa pod husk, Waste biomass valorization, 10 (2019) 877-888. https://doi.org/10.1007/s12649-017-0152-2 Betiku, A.M. Akintunde, T.V. Ojumu, Banana peels as a biobase catalyst for fatty acid methyl esters production using Napoleon's plume (Bauhinia monandra) seed oil: A process parameters optimization study, Energy, 103 (2016) 797-806. https://doi.org/10.1016/j.energy.2016.02.138 Balajii, S. Niju, A novel biobased heterogeneous catalyst derived from Musa acuminata peduncle for biodiesel production–Process optimization using central composite design, Energy Conversion Management, 189 (2019) 118-131. https://doi.org/10.1016/j.enconman.2019.03.085 Betiku, A.O. Etim, O. Pereao, T.V. Ojumu, Two-step conversion of neem (Azadirachta indica) seed oil into fatty methyl esters using a heterogeneous biomass-based catalyst: An example of cocoa pod husk, Energy Fuels, 31 (2017) 6182-6193. https://doi.org/10.1021/acs.energyfuels.7b00604 Hamid Khashan, M., Mohammad, A. K. (2022). 'Comparative study for Pb2+ adsorption from simulated wastewater of battery manufacture on activated carbon prepared from rice husk with different activation agents', Al-Qadisiyah Journal for Engineering Sciences, 15(3), pp. 147-155. https://doi.org/10.30772/qjes.v15i3.827
Statistics Article View: 2,628 PDF Download: 436