Hathot, S., Al dabbagh, B., Aboud, H. (2024). Effects of Dy2O3 doping on physical and mechanical characteristics of B2O3-TeO2-BaO glass. , 42(10), 1210-12219. doi: 10.30684/etj.2024.145037.1649
Saba F. Hathot; Balqees M. Al dabbagh; Haydar Aboud. "Effects of Dy2O3 doping on physical and mechanical characteristics of B2O3-TeO2-BaO glass". , 42, 10, 2024, 1210-12219. doi: 10.30684/etj.2024.145037.1649
Hathot, S., Al dabbagh, B., Aboud, H. (2024). 'Effects of Dy2O3 doping on physical and mechanical characteristics of B2O3-TeO2-BaO glass', , 42(10), pp. 1210-12219. doi: 10.30684/etj.2024.145037.1649
Hathot, S., Al dabbagh, B., Aboud, H. Effects of Dy2O3 doping on physical and mechanical characteristics of B2O3-TeO2-BaO glass. , 2024; 42(10): 1210-12219. doi: 10.30684/etj.2024.145037.1649

Effects of Dy2O3 doping on physical and mechanical characteristics of B2O3-TeO2-BaO glass

Engineering and Technology Journal
Volume 42, Issue 10, October 2024, Pages 1210-12219    PDF (1.64 M)
Document Type: Research Paper
DOI: 10.30684/etj.2024.145037.1649
Authors
Saba F. Hathot* 1; Balqees M. Al dabbagh1; Haydar Aboud2
1Applied Science Dept., University of Technology-Iraq, Alsina’a street, 10066 Baghdad, Iraq
2Faculty of science- physics Dep, Al-Mustansiriya University, Baghdad, Iraq.
Abstract
A new oxide glass host of the form (50-x) B2O3-25TeO2-25BaO-xDy2O3 (where x was varied from 0 to 1.25 mol%) was prepared using the conventional melt-cast quenching method. The study investigated how the glasses' structural, physical, and elastic properties were affected by varying amounts of Dy2O3. The XRD patterns of the samples indicated that they possessed an amorphous nature. FTIR spectrum displayed the vibration mode of trigonal and bipyramidal units like TeO3, TeO4, BO4, and BO3 together with Te-O-Te and Te-O linkages, indicating bridging oxygen (BO). The observed increase in the density (from 4.535 - 4.772 gm.cm-3) was ascribed to the network structure contraction. The improvement in the elastic moduli of the glasses (obtained from the measured shear and longitudinal acoustic velocity) was mainly due to Dy2O3 doping with higher molecular weight. Consequently, it increased the glass rigidity by forming more BO in the glass network, altering the physical and structural characteristics. The obtained rise in the Debye temperature (from 334.0107–351.383 K) and softening temperature (from 399.6075-451848 K) was due to BO-mediated changes in CN. (coordination number) of the glass network. It was shown that the mechanical and structural characteristics of the proposed glass host can be tailored by tuning the Dy2O3 contents. These glasses may be useful for making high-strength optical fibers. 

Highlights
  • Barium-boro-tellurite glasses with 0-1.25% Dy2O3 were made using melt-quench method
  • Glasses were characterized to evaluate the effects of varying Dy2O3 content on properties
  • Increasing Dy2O3 density by modifying the glass network created a more compact, connected structure
  • FTIR analysis provided chemical bonding and vibration information as a function of Dy2O3 content
  • Mechanical properties improved with increased BO bonds forming from Dy2O3, enhancing rigidity
Keywords
Glass host; Dy2O3; BO; FTIR; Elastic constant
References
  1. Kaur, A. Khanna, L.I. Aleksandrov, Structural, thermal, optical and photo-luminescent properties of barium tellurite glasses doped with rare-earth ions, J. Non-Cryst. Solids, 476 (2017) 67-74. https://doi.org/10.1016/j.jnoncrysol.2017.09.025
  2. Tagiara, D. Palles, E. Simandiras, V. Psycharis, A. Kyritsis, E. Kamitsos, Synthesis, thermal and structural properties of pure TeO2 glass and zinc-tellurite glasses, J. Non-Cryst. Solids, 457 (2017) 116-125. https://doi.org/10.1016/j.jnoncrysol.2016.11.033
  3. Kaur, A. Khanna, C. Pesquera, F. González, V. Sathe, Preparation and characterization of lead and zinc tellurite glasses, J. Non-Cryst. Solids, 356 (2010) 864-872. https://doi.org/10.1016/j.jnoncrysol.2010.01.005
  4. Pawar, S. Munishwar, R. Gedam, I. white light luminescent Dy, doped lithium borate glasses for W-LED: a correlation between physical, thermal, structural and optical properties, Solid State Sci., 64 (2017) 41-50. https://doi.org/10.1016/j.solidstatesciences.2016.12.009
  5. F. Hathot, N.J. Jubier, R.H. Hassani, A. Salim, Physical and elastic properties of TeO2-Gd2O3 glasses: Role of zinc oxide contents variation, Optik, 247 (2021) 167941. https://doi.org/10.1016/j.ijleo.2021.167941
  6. Umar, M. Halimah, M. Azlan, L. Grema, G. Ibrahim, A. Ahmad, A. Hamza, M. Dihom, Structural, elastic and thermo-physical properties of Er 2 O 3 nanoparticles doped bio-silicate borotellurite glasses, SN Appl. Sci., 2 (2020) 1-10. https://doi.org/10.1007/s42452-020-2112-x
  7. Abdulbaset, M. Halimah, S. Alazoumi, S. Umar, G. Ibrahim, Elastic properties of TeO2–ZnO–Ag2O doped with Nd2O3, Mater. Chem. Phys., 260 (2021) 124195. https://doi.org/10.1016/j.matchemphys.2020.124195
  8. K. Halimah, M.N.A. Hazlin, F.D. Muhammad, Experimental and theoretical approach on the optical properties of zinc borotellurite glass doped with dysprosium oxide, Spectrochim. Acta - A: Mol. Biomol. Spectrosc., 195 (2018) 128-135. https://doi.org/10.1016/j.saa.2017.12.054
  9. Nalin, M. Poulain, S. Ribeiro, Y. Messaddeq, Crystallization study of the (1− x) Sb2O3–(x) SbPO4 glass system, Mater. Chem. Phys., 112 (2008) 1069-1073. https://doi.org/10.1016/j.matchemphys.2008.07.033
  10. D. Tatar, G. Özen, F. Erim, M. Öveçoǧlu, Raman characterizations and structural properties of the binary TeO2- WO3, TeO2- CdF2 and ternary TeO2- CdF2-WO3 glasses, J. Raman Spectrosc., 41 (2010) 797-807. https://doi.org/10.1002/jrs.2519
  11. A. Aziz Sidek, S. Rosmawati, M.K. Halimah, K.A. Matori, Z.A. Talib, Effect of AlF 3 on the Density and Elastic Properties of Zinc Tellurite Glass Systems, Materials, 5 (2012) 1996-1944. https://doi.org/10.3390/ma5081361
  12. Elkhoshkhany, R. El-Mallawany, E. Syala, Mechanical and thermal properties of TeO2–Bi2O3–V2O5–Na2O–TiO2 glass system, Ceram. Int., 42 (2016) 19218-19224. https://doi.org/10.1016/j.ceramint.2016.09.086
  13. B. Saddeek, N. Elsayed, Structural and mechanical features of some lanthanum tellurite glasses, Can. J. Phys., 93 (2015) 460-465. https://doi.org/10.1139/cjp-2014-0044
  14. Elkhoshkhany, R. Abbas, R. El-Mallawany, A. Fraih, Optical properties of quaternary TeO2–ZnO–Nb2O5–Gd2O3 glasses, Ceram. Int., 40 (2014) 14477-14481. https://doi.org/10.1016/j.ceramint.2014.07.006
  15. Mohd Fudzi, H. Mohamed Kamari, A. Abd Latif, A. Muhammad Noorazlan, Linear optical properties of zinc borotellurite glass doped with lanthanum oxide nanoparticles for optoelectronic and photonic application, J. Nanomater., 2017 (2017). https://doi.org/10.1155/2017/4150802
  16. Rajiv, M.S. Reddy, J. Uchil, C.N. Reddy, Thermal and Optical properties of Sodium-Phospho-Zinc-Neodymium oxide glass system, J. Adv. Sci. Res., 5 (2014) 32-39.
  17. Kamalaker, G. Upender, C. Ramesh, V.C. Mouli, Raman spectroscopy, thermal and optical properties of TeO2–ZnO–Nb2O5–Nd2O3 glasses, Spectrochim. Acta, Part A, 89 (2012) 149-154. https://doi.org/10.1016/j.saa.2011.12.057
  18. Halimah, S. Umar, K. Chan, A. Latif, M. Azlan, A. Abubakar, A. Hamza, Study of rice husk silicate effects on the elastic, physical and structural properties of borotellurite glasses, Mater. Chem. Phys., 238 (2019) 121891. https://doi.org/10.1016/j.matchemphys.2019.121891
  19. Mhareb, R. Alsharhan, M. Sayyed, Y. Alajerami, M. Alqahtani, T. Alayed, M. Almurayshid, The impact of TeO2 on physical, structural, optical and radiation shielding features for borate glass samples, Optik, 247 (2021) 167924. https://doi.org/10.1016/j.ijleo.2021.167924
  20. F. Ahmed, S.O. Ibrahim, M.R. Sahar, S.Q. Mawlud, Effect of Rare Earth Co-Doping On Physical and Optical Characterization of Zinc Tellurite Glass Embedded Ag NPs, ZANCO J. Pure Appl. Sci., 28 (2017) 68-73.
  21. G. Pavani, K. Sadhana, V.C. Mouli, Optical, physical and structural studies of boro-zinc tellurite glasses, Physica B, 406 (2011) 1242-1247. https://doi.org/10.1016/j.physb.2011.01.006
  22. S. Yousef, A. Al-Salami, M. Hotzel, Optical and thermal characteristics of glasses based on TeO2, Bull. Mater. Sci., 35 (2012) 961-967. https://doi.org/10.1007/s12034-012-0393-4
  23. A. Hazlin, M. Halimah, F. Muhammad, M. Faznny, Optical properties of zinc borotellurite glass doped with trivalent dysprosium ion, Physica B: Condens. Matter., 510 (2017) 38-42. https://doi.org/10.1016/j.physb.2017.01.012
  24. R. Mohamad Azaludin, N.S. Sabri, Infrared spectroscopy of mixed glass former effect in borotellurite glasses: A review, Gading J. Sci. Technol., 4 (2021) 94-102.https://ir.uitm.edu.my/id/eprint/46258
  25. Elkhoshkhany, N. Samir, Structural, thermal and optical properties of oxy-fluoro borotellurite glasses, J. Mater. Res.Technol., 9 (2020) 2946-2959. https://doi.org/10.1016/j.jmrt.2020.01.045
  26. O’Donnell, C. Miller, D. Furniss, V. Tikhomirov, A. Seddon, Fluorotellurite glasses with improved mid-infrared transmission, J. Non-Cryst. Solids, 331 (2003) 48-57. https://doi.org/10.1016/j.jnoncrysol.2003.08.081
  27. Nanda, N. Berwal, R. Kundu, R. Punia, N. Kishore, Effect of doping of Nd3+ ions in BaO–TeO2–B2O3 glasses: A vibrational and optical study, J. Mol. Struct., 1088 (2015) 147-154. https://doi.org/10.1016/j.molstruc.2015.02.021
  28. Ghoshal, A. Awang, M. Sahar, R.J. Amjad, M.R. Dousti, Spectroscopic and structural properties of TeO2-ZnO-Na2O-Er2O3-Au glasses, Chalcogenide Lett., 10 (2013) 411-420.
  29. Alazoumi, H. Sidek, M. Halimah, K. Matori, M. Zaid, A. Abdulbaset, synthesis and elastic properties of ternary ZnO-PbO-TeO2 GLASSES, Chalcogenide Lett., 14 (2017).
  30. B. Saddeek, H. Afifi, N. Abd El-Aal, Interpretation of mechanical properties and structure of TeO2–Li2O–B2O3 glasses, Phys. B: Condens. Matter, 398 (2007) 1-7. https://doi.org/10.1016/j.physb.2007.04.011
  31. El-Mallawany, H. Afifi, M. El-Gazery, A. Ali, Effect of Bi2O3 addition on the ultrasonic properties of pentaternary borate glasses, Measurement, 116 (2018) 314-317. https://doi.org/10.1016/j.measurement.2017.11.028
  32. Eevon, M. Halimah, Z. Azmi, C. Azurahanim, Elastic properties of TeO2-B2O3—ZnO-Gd2O3 glasses using non-destructive ultrasonic technique, Chalcogenide Lett., 13 (2016) 281-289.
  33. Elokr, Y. Abou Deif, Optical, elastic properties and DTA of TNZP host tellurite glasses doped with Er3+ ions, J. Mol. Struct., 1108 (2016) 257-262. https://doi.org/10.1016/j.molstruc.2015.11.066
  34. A. Al-Shamiri, A. Eid, Optical and ultrasonic properties of chromium oxide in sodium zinc phosphate glass, Photon. Optoelectron., 1 (2012) 1-8.
  35. Halimah, H. Sidek, W. Daud, H. Zainul, Z. Talib, A. Zaidan, A. Zainal, H. Mansor, Ultrasonic study and physical properties of borotellurite glasses, Am. J. Appl. Sci., 2 (2005) 1541-1546.
  36. Sidek, S. Rosmawati, B. Azmi, A. Shaari, Effect of ZnO on the thermal properties of tellurite glass, Adv. Condens. Matter. Phys., 2013 (2013).https://doi.org/10.1155/2013/783207
  37.  A. Abd El-Moneim, I. Youssof, L. Abd El-Latif, Structural role of RO and Al2O3 in borate glasses using an ultrasonic technique, Acta Mater., 54 (2006) 3811-3819. https://doi.org/10.1016/j.actamat.2006.04.012
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