Ibraheem, E., Bdaiwi, W. (2024). Enhancement of mechanical properties in unsaturated polyester via reinforcement with olive leaf particles. , 42(10), 1267-1276. doi: 10.30684/etj.2024.150924.1772
Eman K. Ibraheem; Waleed Bdaiwi. "Enhancement of mechanical properties in unsaturated polyester via reinforcement with olive leaf particles". , 42, 10, 2024, 1267-1276. doi: 10.30684/etj.2024.150924.1772
Ibraheem, E., Bdaiwi, W. (2024). 'Enhancement of mechanical properties in unsaturated polyester via reinforcement with olive leaf particles', , 42(10), pp. 1267-1276. doi: 10.30684/etj.2024.150924.1772
Ibraheem, E., Bdaiwi, W. Enhancement of mechanical properties in unsaturated polyester via reinforcement with olive leaf particles. , 2024; 42(10): 1267-1276. doi: 10.30684/etj.2024.150924.1772

Enhancement of mechanical properties in unsaturated polyester via reinforcement with olive leaf particles

Engineering and Technology Journal
Volume 42, Issue 10, October 2024, Pages 1267-1276    PDF (1.24 M)
Document Type: Research Paper
DOI: 10.30684/etj.2024.150924.1772
Authors
Eman K. Ibraheem* ; Waleed Bdaiwi
Department of Physics, College of Education for Pure Sciences, University of Anbar, Anbar, Iraq.
Abstract
The use of olive leaf powder (OLP) as a filler material in unsaturated polyester composites brings a new avenue for the development of mechanical and thermal properties. The present work focuses on the impact of the relative proportions of OLP ranging from (0, 5, 10, 15, 20, and 25%) on the structural, electrical, and thermal properties of the composites.The specimens were prepared through the hand lay molding process, and the hardness strength, impact strength as well as compressive strength examination were conducted.These findings suggest that the characteristics of these composites improve as the content of OLP increases.The maximum impact strength found is 2.52 KJ/m², and the maximum hardness is 7.24 N/mm², while the compressive strength is around 48.7 MPa. Thermal conductivity decreased on the volumetric fraction of 25%, which is within the range of 0.101 W/m·℃. Based on the analysis of the FTIR results, it can be claimed that the change in intensities and positions of the peaks may be associated with the interaction between the OLP and the polyester matrix. The SEM data suggest that the OLP is dispersed throughout the matrix, and strong interfacial adhesion exists between them. In summary, this work highlights the prospects of using OLP-filled unsaturated polyester composites for several purposes due to the improved mechanical and thermal characteristics.

Highlights
  • A new type of polymer matrix composite, pls and plo, was used.
  • Adding particles significantly enhanced impact resistance for all samples.
  • Thermal conductivity decreased for all samples.
  • FTIR spectra showed chemical adhesion between olp and the matrix, confirmed by SEM photomicrographs.
  • The particles can be used in mechanical applications requiring high mechanical and thermal insulation properties.
Keywords
Biocomposites; Mechanical Properties; Olive Leaf Powder; Thermal Conductivity; Unsaturated Polyester
References
  1. Mohanty, K. Misra, M. Drzal, T. Natural fibers, biopolymers, and biocomposites, CRC press. , 2005.
  2. Clyne, W. Hull, D. An introduction to composite materials. Cambridge university press, 2019.
  3. K. Friedrich, A. Almajid, Manufacturing aspects of advanced polymer composites for automotive applications, Appl. Compos . Mater., 20 (2013)107-128. https://doi.org/10.1007/s10443-012-9258-7
  4. Ashby, F. Johnson, K. Materials and design: the art and science of material selection in product design, 2013.
  5. .Chawla, K. Composite materials: science and engineering, Springer Science & Business Media, 2012.
  6. Miracle, D.B. and S.L. Donaldson. 2001. Introduction to composites, ASM Handbook, Vol. 21, pp. 1113 – 1136. ASM International. https://doi.org/10.31399/asm.hb.v21.a0003487
  7. O. Faruk, A.K. Bledzki, H.P. Fink, M. Sain‏, Biocomposites reinforced with natural fibers: 2000–2010, Prog. Polym. Sci., 37 (2012) 1552-1596. https://doi.org/10.1016/j.progpolymsci.2012.04.003
  8. A. Bledzki, J. Gassan, Composites reinforced with cellulose based fibres, Prog. Polym. Sci., 24 (1999) 221-274. https://doi.org/10.1016/S0079-6700(98)00018-5
  9. Idicula , A. Boudenne , L. Umadevi , L. Ibos , Y. Candau , S.Thomas , Thermophysical properties of natural fibre reinforced polyester composites, Compos. Sci. Technol., 66 (2006) 2719-2725. https://doi.org/10.1016/j.compscitech.2006.03.007
  10. H. Salah, Study the mechanical properties of epoxy resin reinforcement by ziziphus spina-christi powder, J. Eng. Sci., 15 (2022) 42-47. https://doi.org/10.30772/qjes.v15i1.845
  11. C. Calvano, A. Tamborrino, Valorization of olive by-products: Innovative strategies for their production, treatment and characterization, Foods, 11 (2022) 768. https://doi.org/10.3390/foods11060768
  12. S. Sismanoglu, U. Tayfun, P. Carmen-Mihaela ,Y. Kanbur, Effective use of olive pulp as biomass additive for eco-grade TPU-based composites using functional surface modifiers, Biomass Conv. Bioref., 13 (2023) 12303-12318. https://doi.org/10.1007/s13399-021-01987-9
  13. B. Rashid, M. Jawaid, H. Fouad, N. Saba, S. Awad, E. Khalaf, M. Sain, Improving the thermal properties of olive /bamboo fiber‐based epoxy hybrid composites, Polym. Compos., 43 (2022) 3167-3174. https://doi.org/10.1002/pc.26608
  14. S. Kalia, B. Kaith, I. Kaur, Pretreatments of natural fibers and their application ng material in polymer composites—a review, Polym. Eng. Sci., 49 (2009)1253-1272. https://doi.org/10.1002/pen.21328
  15. F. Al-Oqla, M. Alaaeddin, Y. El-Shekeil,Thermal stability and performance trends of sustainable lignocellulosic olive/low density polyethylene biocomposites for better environmental green materials, Eng. Solid Mech., 9 (2021 ) 439-448. http://dx.doi.org/10.5267/j.esm.2021.5.002
  16. S. Valvez, A. Maceiras, P.Santos, P. Reis, Olive stones as filler for polymer-based composites: A review, Materials, 14 (2021) 845. https://doi.org/10.3390/ma14040845
  17. S. Sarmin, M. Jawaid, S. Awad, N. Saba, Olive fiber reinforced epoxy composites: Dimensional Stability, and mechanical properties, Polym. Compos., 43 (2022) 358-365. http://dx.doi.org/10.1002/pc.26380
  18. K. Senthilkumar , M. Chandrasekar, O. Alothman, H. Fouad , M. Jawaid , M. Azeem, Flexural, impact and dynamic mechanical analysis of hybrid composites: Olive tree leaves powder/pineapple leaf fibre/epoxy matrix, J. Mate. Res. Technol., 21 (2022) 4241-4252. https://doi.org/10.1016/j.jmrt.2022.11.036
  19. K. Senthilkumar, M. Chandrasekar, M. Jawaid, M. Mahmoud, H. Fouad, C. Santulli, Sh. Zaki, Investigating the synergistic effect of olive trunk leaves powder and pineapple leaf fibers on the physical, tensile, and thermal properties of epoxy‐based composites, Polym. Compos., 44 (2023) 3416-3424. https://doi.org/10.1002/pc.27330
  20. S. Sarmin, M. Jawaid, M. Mahmoud, N. Saba, H. Fouad, O. Alothman, Mechanical and physical properties analysis of olive biomass and bamboo reinforced epoxy-based hybrid composites, Biomass Conv. Bioref., 14 (2024) 7959-7969. https://doi.org/10.1007/s13399-022-02872-9
  21. Peters, S.T. Handbook of composites; Springer Science & Business Media, 2013.
  22. R. Panneerdhass , A. Gnanavelbabu, K. Rajkumar, Mechanical properties of luffa fiber and ground nut reinforced epoxy polymer hybrid composites, Proc. Eng., 97 (2014) 2042-2051. https://doi.org/10.1016/j.proeng.2014.12.447
  23. Standard test method for tensile properties of plastics, D638-14, ASTM International, 2014.
  24. Askeland, D.R., Phulé, P.P. , Wright, W.J. , and Bhattacharya D.K. The science and engineering of materials; Springer Dordrecht, 2003. https://doi.org/10.1007/978-94-009-1842-9
  25. G. Maradini, M. Oliveira, G. Guanaes, G. Passamani, L. Carreira, W. Boschetti, S. Monteiro, A. Pereira , B. Oliveira , Characterization of polyester nanocomposites reinforced with conifer fiber cellulose nanocrystals, Polymers, 12 (2020) 2838. https://doi.org/10.3390/polym12122838
  26. P. Wambua, J. Ivens, I. Verpoest, Natural fibres: can they replace glass in fibre reinforced plastics? Compos. Sci. Technol., 63 (2003) 1259-1264. https://doi.org/10.1016/S0266-3538(03)00096-4
  27. K. Pickering, M. Efendy, T. Le, A review of recent developments in natural fibre composites and their mechanical performance, Compos. - A: Appl. Sci. Manuf., 83 (2016) 98-112. https://doi.org/10.1016/j.compositesa.2015.08.038
  28. M. Sanjay, G. Arpitha, L. Naik, K. Gopalakrishna, B. Yogesha, Applications of natural fibers and its composites: an overview, Nat. Resour., 7 (2016) 108-114. http://dx.doi.org/10.4236/nr.2016.73011
  29. M. Paauw, A. Pizzi, Completion of unsaturated polyesters analysis by FTIR, J. Appl. Polym. Sci., 48 (1993) 931-934. https://doi.org/10.1002/app.1993.070480517
  30. F. Dawood, W. Bdaiwi, Manufacture of wood processor from unsaturated polyester foam and walnut husk waste, Des. Eng., 7 (2021) 2648-2663.
  31. S. Kamel, Studying some of the mechanical properties of unsaturated polyester reinforced by re-cycled natural materials, J. Eng. Sci., 8 (2015) 137-146.
  32. R.A. Abbas‏, Study What Can be Achieved by the Lack of Flexural Strain Energy of Change for The Efficient Recovery of Novolak of The Elasticity As a Result of Fiber-Reinforcement, Eng. Technol. J., 30 (2012) 284-301. https://doi.org/10.30684/etj.2012.57265
  33. Q. Meng, J. Hu, A review of shape memory polymer composites and blends, Compos. - A: Appl. Sci. Manuf., 40 (2009) 1661-1672. https://doi.org/10.1016/j.compositesa.2009.08.011
  34. F. Zhang, Y. Feng, W. Feng, Three-dimensional interconnected networks for thermally conductive polymer composites: Design, preparation, properties, and mechanisms, Mater. Sci. Eng. R: Reports, 142 (2020) 100580. https://doi.org/10.1016/j.mser.2020.100580
  35. K. Adekunle, C. Sung-Woo, R. Ketzscher, M. Skrifvars, Mechanical properties of natural fiber hybrid composites based on renewable thermoset resins derived from soybean oil, for use in technical applications, J. Appl. Polym. Sci., 124 (2012) 4530-4541. https://doi.org/10.1002/app.35478
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