synthesis and characterization of 1,2,4-traiazole derivative from methyl benzaoate with sulfur bridge links

Ahmed, Ahmed; Tariq, Noor; Abdo Ahmed, Waled; Redwan, Amamer M.

doi:10.37652/juaps.2024.147525.1212

	synthesis and characterization of 1,2,4-traiazole derivative from methyl benzaoate with sulfur bridge links
Journal of University of Anbar for Pure Science
Volume 18, Issue 2, December 2024, Pages 123-129 PDF (532.27 K)
Document Type: Research Paper
DOI: 10.37652/juaps.2024.147525.1212
Authors
Ahmed Ahmed^* ¹; Noor Tariq¹; Waled Abdo Ahmed²; Amamer M. Redwan³
¹Department of Chemistry, College of Science, Al-Nahrain University, Jadriah, Baghdad, Iraq
²Department of Chemistry, Faculty of Education, Thamar University, Dhamar 87246, Yemen
³Department of Chemistry, Faculty of Science, Bani Waleed University, Bani Waleed, Libya
Abstract
The basic nucleus S-(4-(((E)-benzylidene)amino)-5-phenyl-4H-1,2,4-triazol-3-yl) 2-((4-(((E)-benzylidene)amino)-5-phenyl-4H-1,2,4-triazol-3-yl)thio) ethanethioate T.4 produced with many steps, from the cyclization of T.2 with carbon disulfide/ potassium hydroxide using ethanol as a solvent followed by the addition of hydrazine hydrate for 12 hours while experiencing reflux. To create the Schiff base T.3, the successfully synthesized by reflux of T.2 with 1,4-dicarbaldehyde then react T.3 with chemical was exposed to condensation with chloroacetyl chloride. Physical characteristics, such as the melting point, and spectroscopic analysis were used to confirm the compounds (FT-IR) and (1H- NMR).The basic nucleus S-(4-(((E)-benzylidene)amino)-5-phenyl-4H-1,2,4-triazol-3-yl) 2-((4-(((E)-benzylidene)amino)-5-phenyl-4H-1,2,4-triazol-3-yl)thio) ethanethioate T.4 produced with many steps, from the cyclization of T.2 with carbon disulfide/ potassium hydroxide using ethanol as a solvent followed by the addition of hydrazine hydrate for 12 hours while experiencing reflux. To create the Schiff base T.3, the successfully synthesized by reflux of T.2 with 1,4-dicarbaldehyde then react T.3 with chemical was exposed to condensation with chloroacetyl chloride. Physical characteristics, such as the melting point, and spectroscopic analysis were used to confirm the compounds (FT-IR) and (1H- NMR).
Keywords
Schiff base; Triazole derivative; Synthesis; hydrazide

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