Searan, T., Sirhan, M., Hussein, H. (2024). Removal of Succinic and Phthalic Acid from Aqueous Solutions Using Activated Charcoal Prepared from the Desert Plant. , 14(2), 11-25. doi: 10.36531/ijds.2024.149153.1073
Tuka Mahroos Searan; Muthana Mohammed Sirhan; Hanaa Hassan Hussein. "Removal of Succinic and Phthalic Acid from Aqueous Solutions Using Activated Charcoal Prepared from the Desert Plant". , 14, 2, 2024, 11-25. doi: 10.36531/ijds.2024.149153.1073
Searan, T., Sirhan, M., Hussein, H. (2024). 'Removal of Succinic and Phthalic Acid from Aqueous Solutions Using Activated Charcoal Prepared from the Desert Plant', , 14(2), pp. 11-25. doi: 10.36531/ijds.2024.149153.1073
Searan, T., Sirhan, M., Hussein, H. Removal of Succinic and Phthalic Acid from Aqueous Solutions Using Activated Charcoal Prepared from the Desert Plant. , 2024; 14(2): 11-25. doi: 10.36531/ijds.2024.149153.1073

Removal of Succinic and Phthalic Acid from Aqueous Solutions Using Activated Charcoal Prepared from the Desert Plant

IRAQI JOURNAL OF DESERT STUDIES
Article 2, Volume 14, Issue 2, December 2024, Pages 11-25    PDF (1.36 M)
Document Type: Research Paper
DOI: 10.36531/ijds.2024.149153.1073
Authors
Tuka Mahroos Searan* 1; Muthana Mohammed Sirhan1; Hanaa Hassan Hussein2
1Department of Chemistry/ College of Education for Pure Sciences/ University of Anbar / Ramadi / Iraq
2Department of Chemistry / College of Sciences/ Mustansiriyah University/ Baghdad / Iraq
Abstract
Because of its effects on ecosystems and human health, environmental pollution including dangerous organic compounds is one of the most pressing problems in the world. Through this work, the Salsola plant a type of desert plant, was used to prepare activated carbon using hydrogen peroxide as activation agent and use it as an adsorbent surface to remove succinic and phthalic .It was diagnosed by different techniques such as FT-IR, XRD, FESEM, TEM and EDX. It was revealed from FT-IR that it contains OH, CH, C-C, C=O. As functional groups. The results of XRD, FESEM, TEM, and EDX showed the crystalline level of the prepared charcoal and the shape of (pores) on the surface of the activated charcoal.The outer and inner surface area was determined using methylene blue and iodine index.The effect of initial concentration, temperature, adsorbent dose, and contact time of adsorbents on the adsorption rate was studied. The obtained results showed that adsorbed amount (Qe) increases with increasing initial concentration. However, the removal rate decreases with increasing initial concentration. The adsorption isotherms (Langmuir and Freundlich) were applied and it was found that the adsorption process is fully consistent with (Langmuir and Freundlich) equations. Thermodynamic functions (ΔH, ΔS and ΔG) were calculated and it turned out that the adsorption process is exothermic, as the adsorption increases with increasing temperature. The adsorption process is spontaneous and is accompanied by an increase in randomness, meaning that it is less homogeneous on the surface of the adsorbent than it is in the solution.
Keywords
Salsola plant; Activated carbon; Hydrogen peroxide; Adsorption; Removal
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