Ahmed, H., Aljubouri, A., AL-Kaisy, H. (2025). Investigating the role of solvent extraction in altering pH levels for efficient Neodymium extraction from magnet scrap. , 43(10), 835-851. doi: 10.30684/etj.2025.159446.1948
Huwaidah I. Ahmed; Ali A. Aljubouri; Hanaa A. AL-Kaisy. "Investigating the role of solvent extraction in altering pH levels for efficient Neodymium extraction from magnet scrap". , 43, 10, 2025, 835-851. doi: 10.30684/etj.2025.159446.1948
Ahmed, H., Aljubouri, A., AL-Kaisy, H. (2025). 'Investigating the role of solvent extraction in altering pH levels for efficient Neodymium extraction from magnet scrap', , 43(10), pp. 835-851. doi: 10.30684/etj.2025.159446.1948
Ahmed, H., Aljubouri, A., AL-Kaisy, H. Investigating the role of solvent extraction in altering pH levels for efficient Neodymium extraction from magnet scrap. , 2025; 43(10): 835-851. doi: 10.30684/etj.2025.159446.1948

Investigating the role of solvent extraction in altering pH levels for efficient Neodymium extraction from magnet scrap

Engineering and Technology Journal
Volume 43, Issue 10, October 2025, Pages 835-851    PDF (2.58 M)
Document Type: Research Paper
DOI: 10.30684/etj.2025.159446.1948
Authors
Huwaidah I. Ahmed* 1; Ali A. Aljubouri2; Hanaa A. AL-Kaisy3
1College of Applied Science, University of Technology-Iraq, Alsina’a street, 10066 Baghdad, Iraq. College of Production Engineering and Metallurgy, University of Technology-Iraq, Alsina’a street, 10066 Baghdad, Iraq.
2College of Applied Science, University of Technology-Iraq, Alsina’a street, 10066 Baghdad, Iraq.
3College of Materials Engineering, University of Technology-Iraq, Alsina’a street, 10066 Baghdad, Iraq.
Abstract
Recycling rare earth elements, specifically neodymium from magnet scrap, is crucial for advancing sustainable technologies across various industries. In this research, neodymium was recovered by solvent extraction using a stock solution prepared in 200 mL by dissolving 1 g of neodymium (III) nitrate hexahydrate, Nd(NO3)3.6H2O, in 0.5 M nitric acid. Then, it was mixed with 1 M di-(2-ethylhexyl) phosphoric acid (D2EHPA) in Isopar-L, as the organic phase, and 3 M H2SO4, as the aqueous phase, with an organic/aqueous volume ratio of (1:1). Specifically, the study examined the pH variation of the aqueous phase (from 0.5 to 2). The pH of the solution was measured using a pen-type pH meter, where the stripping agent was HNO3 at a concentration of 6 M. The experiments were conducted using a magnetic stirrer at ambient temperature with an agitation speed of 300 rpm for 24 hours. The concentration of metals was measured using an EDX. The extraction efficiency of neodymium increased from 51.7% at a pH of 0.5 to 82.02% at a pH of 1.5, with a slight decrease observed at pH values of 1.7 and 2. Moreover, samples of Mg-Nd alloy were manufactured with various extractant Nd contents of (1, 3, 4, and 5%). The microstructure of the alloys, both before and after corrosion in 3.5% NaCl, was examined using a scanning electron microscope (SEM). The results indicated that the alloys consisted primarily of the α-Mg phase and the Mg12Nd phase, and that the corrosion resistance increased with the increasing amount of neodymium.

Highlights
  • At pH ≤ 2, the concentration of rare earth elements and metal ions increased, enhancing the extraction potential.
  • D2EHPA acted as an efficient cation exchanger, releasing H⁺ ions during metal cation uptake.
  • In solvent extraction, precipitated particles promoted rare earth attachment to extractant compounds.
  • The highest neodymium extraction efficiency was achieved at a pH of 1.5.
  • The addition of neodymium to magnesium improved its corrosion resistance.
Keywords
Rare earth; Neodymium; Magnet; Solvent extraction; Corrosion
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