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Synthesis , Characterization and Molar Conductivity Study for Platinum(II) Phthalocyanine Complex and its Derivatives | ||
| Misan Journal of Acodemic Studies | ||
| Article 1, Volume 8, Issue 16, 2010, Pages 31-44 | ||
| Author | ||
| Adil Ali Abdul-Hassan | ||
| Abstract | ||
| Abstract : A new complexes of platinum (II) phthalocyanine and its derivatives have been prepared , These complexes have been characterized by IR , U.V-visible spectroscopy and molar conductivity measurements . The molar conductivities have been measured in dimethylsulfoxide (DMSO) , methylene chloride (CH2Cl2) and acetonitrile (CH2CN) solvents at room temperature at 10-3 M . Conductivity measurements for all prepared complexes shows that complees behave as weak electrolytes in DMSO , CH3CN and CH2Cl2 solvents in the range 10-5-10-3 M when plotting Λm vs. √c . The conductance data were analyzed by Krauss equation to determine the molar conductivity in infinitely dilution (Λo) and dissociation constant (Kd) to determine the stability of these complexes . The effect of variation in the two parameter (Λo) and (Kd) were fully investigated . | ||
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