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Study and characterization of acetylenn dimmers prepared using Oxidative coupling method | ||
| Diyala Journal For Pure Science | ||
| Article 1, Volume 7, Issue 2, 2011, Pages 32-67 | ||
| Abstract | ||
| In this work five new acetylene dimmers were prepared ( three of them were Homo dimers ) : 1- 1,6-di (thio Benzo thiazol) Hexa 2,4 di(yne) (A) :- 2- 1,6-di(phthalmide) Hexa2,4-diyne (B). 3 - 4 ,5 - di phenyl 3-(2-propanyl) thio -1,2,4 –Triazol (C) (and the other two were Hetro dimmers ) : Hetro dimmer - 1- 1-phthalmide-6-thio benzothiazol hexa 2,4 di-yne (AB ). 2 - 1-phthalmide-6-[4,5-di phenyl-3-thio 1,2,4 triazol] hexa- 2,4 diyne (AC) Using , Oxidative coupling method from the polymerization of three terminal acetylene monomer prepared for this papas via nucleophilic reaction of the type SN2 between Propargyl bromide and the following reagents : ( a) 1 – S- Propargyl thio benzo thiazol 2 - N-Propargyl phathalamide(b), 3 - 4,5di phenyl 3-(2-propy nyl) thio-1,2,4-- triazol(c) thy were characterized by FT- IR and milting point measurement the results were corresponding with the theoretical Assumption the polymerization were underwent in an atmosphere of Oxygen in basic solution using copper salts (I) as a catalyst | ||
| Keywords | ||
| Key Word; Acetylene; Dimers; Oxidative Coupling; Conductivity | ||
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