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Reaction Kinetic ofá-methylstyrene (AMS) Hydrogenation | ||
| Engineering and Technology Journal | ||
| Article 1, Volume 27, Issue 7, 2009, Pages 1301-1316 PDF (290.04 K) | ||
| DOI: 10.30684/etj.27.7.7 | ||
| Authors | ||
| Zaidoon M. Shakoor; Mumtaz A. Zablouk; Adel A. Shuhaib | ||
| Abstract | ||
| In this research hydrogenation kinetic of alpha-methylstyrene (AMS) on Pd/Al2O3 catalyst was studied. The reaction is mildly exothermic (ÄH=-109 kJ/mol). Intrinsic kinetic law was investigated under wide range of operating conditions 0.1 and 0.2 gm catalyst loading, 0.5-100 wt% AMS, 10, 15 and 20 bar pressure and 343-373 K temperature. The experiment data are fitted to estimate the kinetic parameters for different reaction mechanisms by using ACM (Aspen Custom Modeler) software. Finally the results of produced reaction mechanisms are compared with experimental results to obtain the optimum reaction mechanism | ||
| Keywords | ||
| methylstyrene; Hydrogenation; mechanism; catalytic reaction | ||
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