Abdullsattar Irzoqi, A. (2011). Synthesis and characterization of some complexes Zn2+, Cd2+, Hg2+ with ligands substitute 4-(dimethylamine) benzylidene. , 16(3), 129-135.
Ahmed Abdullsattar Irzoqi. "Synthesis and characterization of some complexes Zn2+, Cd2+, Hg2+ with ligands substitute 4-(dimethylamine) benzylidene". , 16, 3, 2011, 129-135.
Abdullsattar Irzoqi, A. (2011). 'Synthesis and characterization of some complexes Zn2+, Cd2+, Hg2+ with ligands substitute 4-(dimethylamine) benzylidene', , 16(3), pp. 129-135.
Abdullsattar Irzoqi, A. Synthesis and characterization of some complexes Zn2+, Cd2+, Hg2+ with ligands substitute 4-(dimethylamine) benzylidene. , 2011; 16(3): 129-135.

Synthesis and characterization of some complexes Zn2+, Cd2+, Hg2+ with ligands substitute 4-(dimethylamine) benzylidene

Tikrit Journal of Pure Science
Article 1, Volume 16, Issue 3, 2011, Pages 129-135
Author
Ahmed Abdullsattar Irzoqi
Abstract
In the present work, preparation of two types of aromatic Schiff bases derived by condensation of 2-dimethylbenzildihaid with 1-amino 2-hydroxy 4-sulphoxynaphthaline or 2-aminobanzoic acid.
These ligands have been identified by using IR spectroscopy, UV-visible and melting point measurements.
Their complexes with divalent ion Zn2+, Cd2+, Hg2+ have been prepared and investigated by UV-visible spectroscopy and their molar ratio plots suggest that their composition have the ratio of 2:1(ligand :metal).
These complexes were isolated in the solid state in alkaline media and identified by IR spectroscopy, UV-visible , melting point measurements and electric conductivity studies.
The structure of the complexes was suggested according to the results which show that Complexes of Zn, Hg was octahedral, while Complexes of Cd was tetrahedral in alkaline media.
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