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COPOLYMENRIZATION AND CROSSLINKING OF POLY (VINYL ACRYLATE) WITH VINYLIC MONOMERS | ||
| Tikrit Journal of Pure Science | ||
| Article 1, Volume 15, Issue 2, 2010, Pages 40-50 | ||
| Author | ||
| Entesar Obaid Al-Tamimi | ||
| Abstract | ||
| Number of new saturated poly esters were prepared as derivatives of poly (vinyl acrylate). This polymer was prepared form reaction of poly (vinylalcohol) with acryloyl chloride by condensation method. The synthesized poly (Vinyl acrylate) were allowed to copolymerized with six vinylic monomers including methyl acrylate, methyl methacrylate, acrylonitrile, acrylamide, maleic anhydride and P-toluidine maleimide respectively, and cross–linked via homo polymerization and with cross linking agent. The prepared polymer were react with electrophilic reagents as bromine in (CCL4) and bromine water. Structures conformation of all polymers and copolymers were identified by using F.T.IR spectra-scopy and some of them were proved by using H-NMR in addition to elemental analysis. | ||
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