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Synthesis and characterization of some transition Metal homo binuclear complexes | ||
| Tikrit Journal of Pure Science | ||
| Article 1, Volume 16, Issue 2, 2011, Pages 50-55 | ||
| Author | ||
| Maher A. M. Al-Ta | ||
| Abstract | ||
| Benzilidenedi(benzoylhydrazine) ( )prepared form benzil and benzoylhydrazine, has been isolated and reacted with some transition metal Fe(II), Co(II), Ni(II) and Cu(II) in both neutral and basic media the reactions have shown to yield complexes of the general formulae [ ]X2 and [ ] (where and are the neutral and dibasic forms of the ligand, or ) the complexes are characterized by analytical ,physical and spectral methods . These measurements have shown that the ligand acts as neutral tetradentated in neutral medium, while in the basic medium, the ligand behave as dibasic tetradentated giving binuclear complexes with the most probable octahedral structure. | ||
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