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Synthesis and Characterization of Schiff Bases (derived from p-substituted aniline) and Their Complexes With Co(II) , Ni(II) and Cu(II) | ||
| Tikrit Journal of Pure Science | ||
| Article 1, Volume 13, Issue 1, 2008, Pages 25-27 | ||
| Author | ||
| Akram A. Mohammed | ||
| Abstract | ||
| The synthesis of several new coordination compounds of cobalt (II), nickel (II) and copper (II) with some Schiff bases derived from acetylacetone and p-aminophenol ( ) or p-aminobonzoic acid ( ) are described. The complexes have the general formulae [M(L')2] and [M(L")2]. All the complexes were characterized by molar conductance, magnetic susceptibility, IR and UV-Vis spectra, while cobalt , nickel and copper contents were determined by standard procedures . IR and UV-Vis spectral data and magnetic properties suggest that all the complexes are square-planar. The two ligands coordinate with the metal (II) ion in a bidentate manner through the enolisable carbonyl group of acetylacetone and the azomethine nitrogen atoms. | ||
| Keywords | ||
| Schiff bases; Transition metal Complexes; substituted aniline | ||
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