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Synthesis and characterization of Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes with mixed ligands of α-naphthylamine dithiocarbamate and 1,10-phenanthroline | ||
| Tikrit Journal of Pure Science | ||
| Article 1, Volume 14, Issue 2, 2009, Pages 103-106 | ||
| Author | ||
| Amaal Y. Assaf | ||
| Abstract | ||
| complexes of α -naphthylamine dithiocarbamate of the type [M(α-naph.dtc)2]. Mixed ligands complexes of the type [M(α -naph.dtc)2phen] (phen = 1,10-phenanathroline), M = Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) have been synthesized and characterized by elemental analysis (atomic absorption, EDTA titration), infrared, electronic spectra, molar conductances and magnetic moments measurements. The results suggest a tetrahedral for all metal ions while Cu+2 complex has square planer structure and the hexa coordinated complexes have octahedral structure . | ||
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