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Synthesis and Characterization of Some Transition metal Complexes with sulpher Containing ligand | ||
| Tikrit Journal of Pure Science | ||
| Article 1, Volume 17, Issue 1, 2012, Pages 136-142 | ||
| Author | ||
| Amena F.Al-Omari | ||
| Abstract | ||
| This research include preparing some of new mononuclear complexes for some transition metal Co(ll),Ni(ll),Cu(ll) and Zn(ll) through the reaction of the salt in these elements with ligand bis (N,N-diethyl phenyl butyl dithiocarbamate). The ligand prepared by the reaction of p-Amino N,N-diethyl phenyl dithiocarbamate with 1,4,dibromo butane . which resulted in the formation of the following complexes [M(Et2S2R)2Cl2] .Then these complexes were reacted with monodentate Lewis base (4-Picolin) and neutral bidentate Lewis base (ethylene diamine ) .The result of this reaction gave the complexes [M(Et2S2R)2Cl2L''2] , [M(Et2S2R)2Cl2L'] M=Co(ll),Ni(ll),Cu(ll),Zn(ll) R= p-Amino N.N-diethyl aniline L"= 4-picolin , L'= Ethylenediamine All the prepared complexes have been characterized by element analysis ,molar conductance ,magnetic susceptibility ,infrared and electronic spectral studies. | ||
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