G. Abed, A., B. Shareef, N., J. AL-Nuri, I. (2008). Study of Charge-Transfer Complexes of Salicylideneanilines with Eu(fod)3 in Carbon Tetrachloride by U.V. Spectroscopy. , 19(1), 59-66. doi: 10.33899/rjs.2008.42285
Amel G. Abed; Nada B. Shareef; Isam J. AL-Nuri. "Study of Charge-Transfer Complexes of Salicylideneanilines with Eu(fod)3 in Carbon Tetrachloride by U.V. Spectroscopy". , 19, 1, 2008, 59-66. doi: 10.33899/rjs.2008.42285
G. Abed, A., B. Shareef, N., J. AL-Nuri, I. (2008). 'Study of Charge-Transfer Complexes of Salicylideneanilines with Eu(fod)3 in Carbon Tetrachloride by U.V. Spectroscopy', , 19(1), pp. 59-66. doi: 10.33899/rjs.2008.42285
G. Abed, A., B. Shareef, N., J. AL-Nuri, I. Study of Charge-Transfer Complexes of Salicylideneanilines with Eu(fod)3 in Carbon Tetrachloride by U.V. Spectroscopy. , 2008; 19(1): 59-66. doi: 10.33899/rjs.2008.42285

Study of Charge-Transfer Complexes of Salicylideneanilines with Eu(fod)3 in Carbon Tetrachloride by U.V. Spectroscopy

Rafidain Journal of Science
Article 8, Volume 19, Issue 1, 2008, Pages 59-66    PDF (0 K)
DOI: 10.33899/rjs.2008.42285
Authors
Amel G. Abed; Nada B. Shareef; Isam J. AL-Nuri
Abstract
Salicylideneanilines in CCl4 form 1:1 charge transfer complexes with Eu(fod)3, indicated by the observation of a new longer wavelength band (~435 nm).
Equilibrium constant values (K) for the complexes were obtained by applying Benesi-Hildebrand equation at different temperatures. The thermodynamic parameters ∆H, ∆S and ∆G of the complex formation were determined at these temperatures.
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