Removal of Phenol Pollutants by Modification Molecular Sieves 13X

S. Sabri, Laith; Shanshool, Jabir

doi:10.30684/etj.27.15.13

	Removal of Phenol Pollutants by Modification Molecular Sieves 13X
Engineering and Technology Journal
Article 1, Volume 27, Issue 15, 2009, Pages 2853-2862 PDF (266.25 K)
DOI: 10.30684/etj.27.15.13
Authors
Laith S. Sabri; Jabir Shanshool
Abstract
Molecular sieves type 13X was modified by treatment with saturated solution of urea or thiourea and adding of sodium silicate as binder to give homogeneous admixture in approximate weight percent, 20% urea or thiourea, 30% binder, and 50% MS13X. The samples were dried and shaped in cylindrical particles of about 5mm diameter and 4-8mm length. The FTIR studies show some interaction between the added urea and thiourea with the original substrates. These are mainly hydrogen band type interactions through –NH2 moiety with –OH group of framework oxygen in the substrate or with adsorbed water. The urea displayed more significant interaction with MS13X than thiourea. Molecular sieve 13X and its admixtures with urea and thiourea showed good ability to remove phenol from water. The urea modified sample, which has the largest surface area, was the best adsorbent for phenol followed by thiourea treated sample. Excellent degree of phenol removal, greater than 98% was achieved by using 0.2 l/h flow rate of 10ppm phenolic solution and 56cm bed length at 300C. The increasing of inlet phenol concentration in water affected largely the driving force and the rate of adsorption, resulted also in higher capacities. While the percentage removal of phenol was decreased by fixed other operating conditions
Keywords
Molecular Sieves; urea; thiourea; Phenol Pollutant; adsorption

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