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Preparation and Study of Charge- Transfer Complexes for Acetylenic Amine Derivatives | ||
| Journal of University of Anbar for Pure Science | ||
| Article 8, Volume 4, Issue 2, 2010, Pages 24-26 PDF (477.73 K) | ||
| Document Type: Research Paper | ||
| DOI: 10.37652/juaps.2010.43921 | ||
| Author | ||
| Omar Hamd Shehab* | ||
| AL-Anbar University- College of Education for women | ||
| Abstract | ||
| Acetylenic amine derived from secondary amines such as piperidine , pyrolidine and diethyl amine were synthesized as charge transfer donor have been treated with receptor I2,Br2 and DDQ (DDQ = 2,3-Dichloro-5,6-Dicyano-p-Benzoquinone) to prepare transitional charge complexes . Benesi-Heldbrand equation have been used at (λmax)for formation complexes to calculate potential ionize. Calculation for acetylenic amines derivatives at the first time from transitional energy with studied receptor and calculated equilibrium constant | ||
| Keywords | ||
| preparation; Charge; Transfer Complexes; Acetylenic Amine | ||
| References | ||
|
1- T.F.Rufledge, "Acetylenic compounds", Academic press, London and New York (1969).
2- R.E. Mecmahone, J.Pharma.Sci., 55,457,(1966).
3- N.R.Eston, J.Mol.Chem., 9,456, (1966).
4- M.A.Schwartz, P.Brown and F.M Vane, Arch. Biochem., 121,pp509-516,(1967).
5- W.Wernick and R. Wolffenstein, Chem. Ber., 31,1553(1889).
6- V.B.Mochalin and T.S. Minervina, Zr. Org. Khim.,1(10),1726 (1965).
7- H.A.Benesi and J.H.Heldbrand, J.Am.Chem.Soc., 71,2703 (1949).
8- R.Foster,"Charge-Transfer Complexes ", Academic Press, London and New York (1969).
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