- All Journals
- Al-Qadisiyah University
- Basrah University
- Kirkuk University
- Mosul University
- The Iraqi Borad for Medical Specialization
- University of Anbar
- University of Technology
- Al Mustafa University
- Al-Zahraa University for Women
- Alnoor University
- Kunooz University
- Misan University
- Ninevah University
- Tikrit University
- University of Al-Hamdaniya
- University of Kerbala
Synthesis and Characterization of New Ligand type (N2) and it's polymeric Complexes with (Co (II), Ni (II), Cu (II), and Pd (II)) ions | ||
| journal of kerbala university | ||
| Article 1, Volume 5, Issue 2, 2009, Pages 86-94 PDF (0 K) | ||
| Author | ||
| Ahmad Thabit Numan | ||
| Abstract | ||
| The reaction of acrylamide with diacetylmonoxime was realized under reflux in methanol to give the new bidentate ligand [N-acryloyl-2-3-butaylidine mono-imine mono- oxime] [HL]. This ligand was used as monomer to react with some metal ions (Co(II), Ni(II), Cu(II), and Pd(II)) in methanol in the presence of methyl ethyl keton peroxide as an initiator with (1:1) metal : ligand ratio to give a series of new polymeric complexes of the general formula[Ni(HL)Cl2 .H2O] , [M(HL)Cl2], where ( M= Co(II), Ni(II),Cu(II) , and Pd(II) ). All compounds were characterised by spectroscopic methods (I.R, U.V-Vis), atomic absorption, (EI-mass for the ligand)], microanalysis (C.H.N) along with conductivity measurements. The obtained data propose a tetrahedral structure for Co and Cu complexes and square planar for Ni and Pd complexes. | ||
|
Statistics Article View: 81 PDF Download: 62 |
||