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Synthesis and Characterization of some complex salts of Ti(III) and VO(V) chlorides with pyrrolium , imidazolium , indolium and their benzyl derivative | ||
| Journal of Education and Science | ||
| Article 2, Volume 19, Issue 3, 2007, Pages 13-20 PDF (0 K) | ||
| DOI: 10.33899/edusj.2007.51318 | ||
| Authors | ||
| N. Buttrus; T. Mohanad; I Saeed | ||
| Abstract | ||
| New complexes salts of A2[VOCl5] and A3[TiCl6],where A = , X = H or CH2Ph, were prepared by treatment of above organic salts with metal chloride in (3:1) or (2:1) molar ratio. The new complex salts were characterized by microelemental analysis, conductivity measurements, spectroscopic data (IR and U.V/Visible) as well as the magnetic measurements. These studies confirm that the complex salts are 2:1 electrolytes and the VO (V) or Ti(III) in the anionic moiety of the complex salts achieve octahedral environment. | ||
| Keywords | ||
| metal chloride; microelemental analysis; anionic moiety | ||
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