T.N.Jassim, (2011). A Study of the Third Phase Formation in the Extraction of U(IV) in TBP-HCl System Using Toluene and Kerosene as Diluents. , 24(1), 183-192.
T.N.Jassim. "A Study of the Third Phase Formation in the Extraction of U(IV) in TBP-HCl System Using Toluene and Kerosene as Diluents". , 24, 1, 2011, 183-192.
T.N.Jassim, (2011). 'A Study of the Third Phase Formation in the Extraction of U(IV) in TBP-HCl System Using Toluene and Kerosene as Diluents', , 24(1), pp. 183-192.
T.N.Jassim, A Study of the Third Phase Formation in the Extraction of U(IV) in TBP-HCl System Using Toluene and Kerosene as Diluents. , 2011; 24(1): 183-192.

A Study of the Third Phase Formation in the Extraction of U(IV) in TBP-HCl System Using Toluene and Kerosene as Diluents

Ibn Al-Haitham Journal For Pure And Applied Science
Article 1, Volume 24, Issue 1, 2011, Pages 183-192
Author
Abstract
The extraction of U (IV) in TBP – HCl system, using toluene and kerosene as diluents, was studied. When toluene was used, a single organic phase appeared at all hydrochloric acid concentrations. The extracted species at high [HCl] which is 5-8 M could be a mixture of UCl4-TBP and UCl4.3TBP.When kerosene was used at high [HCl] which was 5-8 M , two immiscible organic phases appeared. The experimental results in light organic phase indicated UCl4-TBP as extracted species while in heavy organic phase, UCl4-TBP was identified, and the UCl4-3TBP was insoluble in kerosene which lead to the formation of third phase.
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