- All Journals
- Al-Qadisiyah University
- Basrah University
- Kirkuk University
- Mosul University
- The Iraqi Borad for Medical Specialization
- University of Anbar
- University of Technology
- Al Mustafa University
- Al-Zahraa University for Women
- Alnoor University
- Kunooz University
- Misan University
- Ninevah University
- Tikrit University
- University of Al-Hamdaniya
- University of Kerbala
Mono, di and trinuclear complexes Co+2,Ni+2,Cu+2,Bi+3 and Sb+3 with bis-(n-butylthio)ethane | ||
| Journal of Education and Science | ||
| Article 2, Volume 19, Issue 4, 2007, Pages 14-22 PDF (0 K) | ||
| DOI: 10.33899/edusj.2007.5914 | ||
| Authors | ||
| S.W. Zeedan; F.T. Saied; N.H. Buttrus | ||
| Abstract | ||
| Abstract This paper describe the preparation of new ligand bis-(n-butylthio)ethane (L) from the reaction of dibromoethane and potassium-n-butylthiolate. Mono nuclear complexes were obtained by direct reaction of the above ligand with CoCl2.6H2O,NiCl2.6H2O and CuCl2.4H2O in 1:1 metal to ligand , while the dinuclear complexes were obtained from the reaction with SbCl3 or Bi(NO3)3 in 2:2 metal to ligand. Trinuclear complexes of general formula [M´2M(L)2X6]Cl2 were obtained from the reaction of [M´2(L)2X6], M´= Sb+3 or Bi+3 with metal chloride in 1:1 molar ratio, M=Co+2, Ni+2 or Cu+2. The prepared complexes were characterized by metal analysis, IR,U.V-visible spectroscopy, conductivity and magnetic measurements. | ||
| Keywords | ||
| ligand bis-(n-butylthio); ethane (L); Mono nuclear | ||
|
Statistics Article View: 309 PDF Download: 323 |
||