Y. J. Al-Hiti, N., F. Hamadi, W., Y.Al- Ani, W. (2012). Synthesis of 6-Aziridineyl and 6-Triazol-yl of D- Glucitol Derivatives. , 6(1), 41-44. doi: 10.37652/juaps.2012.62773
Nabil Y. J. Al-Hiti; Waleed F. Hamadi; Wajeeh Y.Al- Ani. "Synthesis of 6-Aziridineyl and 6-Triazol-yl of D- Glucitol Derivatives". , 6, 1, 2012, 41-44. doi: 10.37652/juaps.2012.62773
Y. J. Al-Hiti, N., F. Hamadi, W., Y.Al- Ani, W. (2012). 'Synthesis of 6-Aziridineyl and 6-Triazol-yl of D- Glucitol Derivatives', , 6(1), pp. 41-44. doi: 10.37652/juaps.2012.62773
Y. J. Al-Hiti, N., F. Hamadi, W., Y.Al- Ani, W. Synthesis of 6-Aziridineyl and 6-Triazol-yl of D- Glucitol Derivatives. , 2012; 6(1): 41-44. doi: 10.37652/juaps.2012.62773

Synthesis of 6-Aziridineyl and 6-Triazol-yl of D- Glucitol Derivatives

Journal of University of Anbar for Pure Science
Article 13, Volume 6, Issue 1, 2012, Pages 41-44    PDF (230.01 K)
Document Type: Research Paper
DOI: 10.37652/juaps.2012.62773
Authors
Nabil Y. J. Al-Hiti1; Waleed F. Hamadi2; Wajeeh Y.Al- Ani3
1University of Anbar - College of Education for pure Science
2University of Anbar - College of Education for women
3University of Anbar - College of Science.
Abstract
1,3 : 2,4 - Di - 0 -ethylidene - 5 -O - tosyl - 6 - ( 2 - cyano -1- aziridineyl ) -6- deoxy-‌D- glucitol (4) , 6- ( 2- acetate -1- aziridineyl ) derivative ( 5 ) and 6- ( 4- bromo methyl - 1,2,3- triazol -1-y1 ) ( 6 ) and the isomer ( 5- bromo methyl -1,2,3 - triazol-1-y1 ) derivative ( 7 ) were prepared from the mono tosylate mono azido derivative ( 3 ).Compound ( 3 ) underwent 1,3 - dipolar cycloaddition reactions with acrylonitrile and vinylacetate to give, the aziridine derivatives ( 4 ) and ( 5 ) via triazoline themolysis respectively, and with proprgyl bromide gave mixtuyre 1,2,3- triazol derivatives ( 6 ) and isomer ( 7 ).
Keywords
synthesis; Aziridineyl; Triazol; Glucitol Derivatives
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