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Synthesis and Characterization of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Hg(II) Complexes with [(N-(N-benzilidin aminoethyl) Iodomethylene Dithiocarbamate] | ||
| Rafidain Journal of Science | ||
| Article 3, Volume 24, Issue 7, 2013, Pages 25-33 PDF (0 K) | ||
| DOI: 10.33899/rjs.2013.77813 | ||
| Author | ||
| Layla J. Althaher | ||
| Abstract | ||
| A new series of transition metal complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Hg(II), with Schiff base (L) (N-(N-benzilidine aminoethyl) iodomethylene dithiocarbamate) is derived from (2- aminoethyldithiocarbamato -iodomethane) and benzoyl, by (1:2) metal to ligand molar ratio. The complexes were characterized by metal analysis, magnetic susceptibility, molar conductance and IR, UV-Vis, spectral studies. The data showed that these complexes have the composition of [ML2Cl2] type. The UV-Vis spectral and magnetic susceptibility of the complexes suggest an octahedral geometry around each central metal ion. | ||
| Keywords | ||
| Schiff Base; complexes; transitions metals | ||
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