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Synthesis and Characterization of 3-Methoxypropyldithiocarbamate Complexes with Iron(II), Cobalt(II), Nickel(II), Copper(II) and Zinc(II) and Their Adducts with Nitrogen Base Ligands | ||
| Rafidain Journal of Science | ||
| Article 6, Volume 24, Issue 7, 2013, Pages 50-59 PDF (0 K) | ||
| DOI: 10.33899/rjs.2013.77816 | ||
| Authors | ||
| Saad E. Al-Mukhtar; Marwa Th. Aghwan | ||
| Abstract | ||
| New complexes of dithiocarbamate of the general formula [M(3-MeoPrdtc)2] and [M(3-MeoPrdtc)2.nL] Where M= Fe(), Co(), Ni(), Cu() and Zn(), and (3-MeoPrdtc) =3-Methoxypropyldithiocarbamate, and n=2 when L= pyridine, Isoquinoline, γ-picoline, 3,5-lutidine, n=1 when L= ethylenediamine, (1,10)-phenanthroline, have been prepared and characterized by metal analyses, infrared, conductance measurements, electronic absorption spectra and suscetptibility measurements. Magnetic moment and electronic spectra, indicate that the complexes of the type [M(3-meoprdtc)2] are of tetrahedral geometry while the complexes of the type [M(3-meoprdtc)2.nL] have octahedral geometry. | ||
| Keywords | ||
| Dithiocarbamate; iron; cobalt; nickel; copper; Zinc; complexes | ||
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