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Synthesis & Identification of Series from New Ligands derived from 5,6-diformyl-4-Chloro methoxy benzene and Complexation of One of Them with (Zn2+ ,Cd2+) | ||
| Iraqi National Journal Of Chemistry | ||
| Article 1, Volume 0, Issue 51, 2014, Pages 316-326 | ||
| Author | ||
| Fatima Abed Wannas alghurabi | ||
| Abstract | ||
| Abstract In this study, four ligands were synthesized from reaction of 2,6-diformyl-4-chloro methoxy benzene with different amino compounds such as( 2-amino furan ,2-amino thiophene ,2-amino thiazole , 2-amino sulphadiazine ) to produce ligands [1-4] ,the synthesized ligands is named {N,N--(5-Chloro-2-Methoxy-1,3-phenylene)bis (Methan-1-yl-ylidene)dithiophen-2-amine(FCM),N,N--(5-Chloro-2-Methoxy-1,3- phenylene)bis(Methan-1-yl-ylidene)difuran-2-amine (TCM),N,N-- (5-Chloro-2-Methoxy-1,3-phenylene)bis (Methan-1-yl-ylidene)dithiazol-2-amine (ZCM),N,N-- (5-Chloro-2-Methoxy-1,3-phenylene) bis(Methan-1-yl-ylidene) (SCM)} respectively.The ligand (ZCM) is used as a ligand with (Zn2+ ,Cd2+) to formation of complexes and study of optimal conditions of complexes (stoichiometric study ,pH ,concentration of metals and ligand ,molar conductance) .All ligands with complexes were studied for antibacterial and antifungi activity.All ligands with complexes were characterized by (H.NMR–spectra ,FT.IR–spectra (C.H.N)-analysis, UV-Vib-spectra) , melting points. | ||
| Keywords | ||
| complexes of; schiff ligand | ||
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